摘要
以PtCl4为活性组分,伯胺J M-T为溶剂,十二烷为稀释剂制备了用于乙炔氢氯化反应的均相非汞催化体系。根据催化体系的XPS、ICP、IR等表征结果,推测了该体系的催化活性中心、反应机制及失活原因。
A non-mercuric homogenous system for the hydrochlorination of acetylene was prepared by using PtCl4 as active component, primary amine JM-T as solvent, and dodecane as diluent. The active center, reaction mechanism and deactivation reasons of this catalyst system were supposed by XPS, IPC, IR, and etc.
出处
《聚氯乙烯》
CAS
2011年第2期30-34,共5页
Polyvinyl Chloride
关键词
非汞催化剂
乙炔氢氯化
均相催化体系
氯乙烯
non-mercuric catalyst
hydrochlorination of acetylene
homogeneous catalyst system
vinyl chloride
