Keggin结构钼磷杂多酸/三聚苯胺掺杂材料的制备、表征及性质研究

Synthesis,characterization and properties of oliganiline doped with molybdophosphoric heteropoly acid

以杂多酸Ｈ３ＰＷ１２－ ｎ ＭｏｎＯ４０·ｘＨ２Ｏ（ ｎ ＝ １，３） 和三聚苯胺Ｈ２Ｎ Ｎ Ｎ ＮＨ２ 为原料制备了钼磷杂多酸／ 三聚苯胺掺杂材料用元素分析、红外光谱、紫外－ 可见光谱、Ｘ射线粉末衍射谱、热重分析等对此材料进行了表征，测定了其在不同有机溶剂（ＤＭＦ，ＮＭＰ，ＣＨＣｌ３） 中的溶解度材料的荧光光谱表明，在３６６ ｎｍ 和８６３ ｎｍ 处均有较好的荧光发射峰．

The materials of oliganiline doped with molybdophosphoric heteropoly acid have been prepared with H 3PW 12- n Mo n O 40 · x H 2O( n =1,3) and H 2N N N NH 2 , these materials were characterized by elemental analysis, IR, UV-Vis, X-Ray and TG. The solubility in DMF, NMP and CHCl 3 were determined. The fluorescence properties showed that there were fluorescenee emission band at 366 nm and 863 nm.