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Keggin结构钼磷杂多酸/三聚苯胺掺杂材料的制备、表征及性质研究 被引量:5

Synthesis,characterization and properties of oliganiline doped with molybdophosphoric heteropoly acid
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摘要 以杂多酸H3PW12- n MonO40·xH2O( n = 1,3) 和三聚苯胺H2N N N NH2 为原料制备了钼磷杂多酸/ 三聚苯胺掺杂材料用元素分析、红外光谱、紫外- 可见光谱、X射线粉末衍射谱、热重分析等对此材料进行了表征,测定了其在不同有机溶剂(DMF,NMP,CHCl3) 中的溶解度材料的荧光光谱表明,在366 nm 和863 nm 处均有较好的荧光发射峰. The materials of oliganiline doped with molybdophosphoric heteropoly acid have been prepared with H 3PW 12- n Mo n O 40 · x H 2O( n =1,3) and H 2N N N NH 2 , these materials were characterized by elemental analysis, IR, UV-Vis, X-Ray and TG. The solubility in DMF, NMP and CHCl 3 were determined. The fluorescence properties showed that there were fluorescenee emission band at 366 nm and 863 nm.
出处 《东北师大学报(自然科学版)》 CAS CSCD 1999年第3期37-41,共5页 Journal of Northeast Normal University(Natural Science Edition)
基金 国家自然科学基金资助项目
关键词 KEGGIN结构 杂多酸 三聚苯胺 掺杂材料 Keggin structure heteropoly acid polyaniline doping material
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参考文献6

  • 1Gong Jian,Sympo Applied Diemistry,1998年,8卷,124页
  • 2李永明,高分子学报,1998年,2卷,177页
  • 3王恩波,多酸化学导论,1998年,72页
  • 4Qu L Y,Synth Metal,1997年,84卷,135页
  • 5Wei Yen,Tetrahedron Lett,1996年,37卷,6期,731页
  • 6耿延候,学位论文,1996年,12页

同被引文献13

  • 1李兴伟,王秀丽,刘国成,林宏艳.[(C_2H_5)_4N]_4GeMo_(12)O_(40)纳米粒子体修饰碳糊电极的制备及其电化学行为研究[J].东北师大学报(自然科学版),2005,37(3):36-40. 被引量:2
  • 2HAGRMAN P J,HAGRMAN D,ZUBIETA J.Organic-inorganic hybrid materials:from simple coordination polymers to organodiamine-templated molybdenum oxides[J].Angew Chem Int Ed,1999,38:2 638-2 684.
  • 3MULLER A,POLARZ S,DAS S K,et al."Open and shut for guests in molybdenum-oxide-based giantspheres,baskets,and rings containing thepentagon as a common structural element[J].Angew Chem Int Ed,1999,38:3 241-3 245.
  • 4BROWN I D,ALTERMATT D.Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database[J].Acta Cryst,1985,B4:244-247.
  • 5CORONADO E,GARCIA C J G.Polyoxometalate-based molecular materials[J].Chem Rev,1998,98:273-296.
  • 6MULLER A,KO;GERLER P.Erratum to "from simple building blocks to structures with increasing size and complexity"[J].Coord Chem Rev,2000,199:335-341.
  • 7GOUZERH P,PROUST A.Main-group element,organic,and organometallic derivatives of polyoxome-talates[J].Chem Rev,1998,98:77-111.
  • 8Gong J,Xiu Junzhong,Wei Xie,et al.The solid-state synthesis of polyaniline/H4SiW12O40 material[J].Synth.,Met.,2002 (129):187-192.
  • 9Gong J,Su Z M,Wang R S,et al.Sytheses,characterization and conductivity of polyaniline doped with H5SiM11VO40(M=Mo,W)[J].Synth.Met.,1999(101):751.
  • 10吕仁庆,马荔,曹作刚,龚剑,瞿伦玉.杂多酸掺杂聚苯胺的表征及催化研究进展[J].东北师大学报(自然科学版),2000,32(1):41-46. 被引量:12

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