摘要
在酸性条件下,用高锰酸钾氧化1,1-二氨基-2,2-二硝基乙烯(FOX-7)时,得到一种非预期的新化合物。通过元素分析、红外、核磁和质谱等波谱分析数据,鉴定样品的结构为1-氯-1,1-二硝基-2-(N-氯脒基)乙烷,并对其裂解途径进行了推断。
In acid condition,1,1-diamino-2,2-dinitroethylene(FOX-7) was oxidized by potassium permanganate,and a new unexpected compound 1-chloro-1,1-dinitro-2-(N-chloroamidino)-ethane was obtainded.The structure of the compound was identified by elemental analysis,IR,NMR,and MS.The fragmentation pathway of MS spectra was discussed as well.
出处
《光谱实验室》
CAS
CSCD
北大核心
2011年第2期818-821,共4页
Chinese Journal of Spectroscopy Laboratory