过渡金属催化醇氧化反应的研究进展

Recent Progress in Oxidation of Alcohols Catalyzed by Transition Metal

氧化醇为相应的羰基化合物在有机化学基础研究及其工业应用中占有非常重要的地位.在众多关于醇氧化反应的研究中,如何使用对环境友好的氧化剂替代传统的氧化剂,选择具有高性能、廉价、清洁、可回收的催化剂,一直是化学工作者研究的一个热点.综述了近年来该研究领域中的一些重要过渡金属催化体系,并简要介绍了各类催化氧化体系的催化效果.

The oxidation of alcohols to the corresponding carbonyl compounds plays an important role in academic research and industrial applications.Among the investigation on the alcohol oxidation,the use of benign oxidants instead of traditional oxidants,and the selectivity of efficient,low-cost,clean and recyclable catalysts have been critical subject to chemical research.The review summarizes the recent and important catalytic systems in this area.The catalytic effect of different catalytic systems is briefly discussed herein.