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含Nd(Ⅲ)配合物的合成、结构及近红外发光性能 被引量：4

Synthesis,structure andnear-infrared luminescence of Nd(Ⅲ) coordination polymer
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摘要 采用恒温磁力搅拌的方法,以1,10-菲啰啉(phen)、对氨基苯甲酸为配体,合成了1种Nd(Ⅲ)配合物[Nd(p-NH2C6H4CO2)3(p-NH2C6H4CO2H)(phen)2].2H2O.2phen,通过X光单晶衍射仪确定了该配合物的晶体结构.并在室温下测定了固态粉末的IR,UV-Vis-NIR光谱以及激发和发射光谱.该配合物在近红外区表现出明显的Nd(Ⅲ)离子特征发射,这主要归功于配体的敏化作用. One new Nd（III） coodination complex with the ligands phen and p-NH2C6H4CO2H,[Nd（p-NH2C6H4CO2）3（p-NH2C6H4CO2H）（phen）2]·2H2O·2phen,has been synthesized by the thermostatic magnetic stirring method.Its structure was determined by single-crystal X-ray diffractometer.At room temperature in the solid state,the IR,UV-Vis-NIR,excitation and emission spectra of the complex were measured.The complex exhibits intense characteristic emissions of Nd（Ⅲ） ion in the NIR region,which should be attributed to the sensitization from the organic ligands.
作者 迟玉贤 刘同帅 李野
机构地区 辽宁师范大学化学化工学院
出处 《辽宁师范大学学报（自然科学版）》 CAS 2011年第1期81-85,共5页 Journal of Liaoning Normal University:Natural Science Edition
基金 国家自然科学基金项目(20571037) 辽宁省教育厅创新团队项目(2007T092)
关键词 Nd(Ⅲ)配合物 近红外发光 晶体结构 Nd（Ⅲ） coordination complex Near-infrared luminescence Crystal structure
分类号 O614.335 [理学—无机化学]
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参考文献11

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共引文献24

同被引文献17

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引证文献4

二级引证文献3

辽宁师范大学学报（自然科学版）
2011年 第1期

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