摘要
A new ligand N,N′ bis[(1 phenyl 3 methyl 5 oxo 4 pyrazolinyl) 2 thenoylmethylidyne]ethyl enediimine (HPMTHP)\-2en and its five complexes have been sythesized. These complexes have the general formula [M(PMTHP)\-2en], where M=Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), Pd(Ⅱ), Pt(Ⅱ). They were characterized by elemental analysis, IR, UV vis, magnetic moments and molar conductance. The results showed that the complexes are all of quadricoordinate square planar geometry. The antibacterial experiment indicated that they have high antibacterial activities against S. aureus, B. subtillis, E. coli, E. carotovora, C. flaccumfaciens.
A new ligand N,N′ bis[(1 phenyl 3 methyl 5 oxo 4 pyrazolinyl) 2 thenoylmethylidyne]ethyl enediimine (HPMTHP)\-2en and its five complexes have been sythesized. These complexes have the general formula [M(PMTHP)\-2en], where M=Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), Pd(Ⅱ), Pt(Ⅱ). They were characterized by elemental analysis, IR, UV vis, magnetic moments and molar conductance. The results showed that the complexes are all of quadricoordinate square planar geometry. The antibacterial experiment indicated that they have high antibacterial activities against S. aureus, B. subtillis, E. coli, E. carotovora, C. flaccumfaciens.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1999年第5期657-660,共4页
Chinese Journal of Inorganic Chemistry
基金
黑龙江省自然科学基金
关键词
酰基吡唑
啉酮
双席夫碱
配合物
缩乙二胺
acylpyrazolone\ \ \ bis schiff base\ \ \ complex\ \ \ bioactivity
