摘要
We consider the covalence characters of the 3d electron with the eg orbital freedoms and put forward a new mechanism of the orbital ordering （00） based on the direct coulomb repulsion in this article. The results show that the orbital-orbital interaction （OO-I） between the adjacent ions in 180-degree configuration is dominated by the superexchange energy accompanied by a weak orbital-spin coupling, and the OO-I in 90-degree configuration is monitored by the oxygen on-site coulomb repulsion. The ferro-OO is the stable ground state for the one-dimensional chain in the case of the 90-degree configuration.
