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Antiplasticizing Effect of MOCA on Poly(vinyl chloride) 被引量：2

Antiplasticizing Effect of MOCA on Poly(vinyl chloride)
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摘要 An obvious antiplasticizing effect has been observed in PVC with small amount of MOCA, 3,3’-dichloro-4,4’-diamino-diphenylmethane. PVC-MOCA interaction and crystallization behavior of PVC/MOCA blends were investigated in detail to explain the mechanism of antiplasticization on the basis of a series of techniques including DMA, FTIR, and DSC. The results of mechanical properties tests show that the tensile strength of PVC with 5 phr of MOCA reaches a maximum value, 69.5 Mpa, which is about 23 % higher than that of pure PVC. The rise in tensile strength was attributed to an antiplasticizing effect of MOCA on PVC as confirmed by DMA measurements. The evidences from FTIR reveal that a strong hydrogen-bonding interaction takes place between the nitrogen atom of –NH2 groups in MOCA and the methine proton of PVC repeat units. The results of DSC analysis indicate that crystallization behavior of MOCA is suppressed completely and the crystallinity of PVC decreases with the increase of MOCA amount. An obvious antiplasticizing effect has been observed in PVC with small amount of MOCA, 3,3’-dichloro-4,4’-diamino-diphenylmethane. PVC-MOCA interaction and crystallization behavior of PVC/MOCA blends were investigated in detail to explain the mechanism of antiplasticization on the basis of a series of techniques including DMA, FTIR, and DSC. The results of mechanical properties tests show that the tensile strength of PVC with 5 phr of MOCA reaches a maximum value, 69.5 Mpa, which is about 23 % higher than that of pure PVC. The rise in tensile strength was attributed to an antiplasticizing effect of MOCA on PVC as confirmed by DMA measurements. The evidences from FTIR reveal that a strong hydrogen-bonding interaction takes place between the nitrogen atom of –NH2 groups in MOCA and the methine proton of PVC repeat units. The results of DSC analysis indicate that crystallization behavior of MOCA is suppressed completely and the crystallinity of PVC decreases with the increase of MOCA amount.
作者 张藕生 张超灿
机构地区 School of Materials Science and Engineering
出处 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2011年第1期83-87,共5页 武汉理工大学学报（材料科学英文版）
基金 Funded by National Natural Science Foundation of China(No.50673080)
关键词 poly（vinyl chloride） MOCA ANTIPLASTICIZATION CRYSTALLINITY INTERACTION poly（vinyl chloride） MOCA antiplasticization crystallinity interaction
分类号 TQ325.3 [化学工程—合成树脂塑料工业] TU242.5 [建筑科学—建筑设计及理论]
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参考文献23

  • 1Kinjo N, Nakagawa T. Antiplasticization in the Slightly Plasticized Poly(vinyl chloride)[J]. Polym. J., 1972, 4: 143-153.
  • 2Bergquist P, Zhu Y, Jones A A, et al. Plasticization and An- tiplasticization in Polycarbonates: The Role of Diluent Mo- tion[J]. Macromolecules, 1999, 32:7 925-7 931.
  • 3Vidotti S E, Chinellato A C, Hu G H, et al. Effects of Low Molar Mass Additives on the Molecular Mobility and Transport Properties of Polysulfone[J]. J. Appl. Polym. Sci., 2006, 101:825-832.
  • 4Garcia A, Iriarte M, Uriarte C, et al. Antiplasticization of a Polyamide: a Positron Annihilation Lifetime Spectroscopy Study[J]. Polymer, 2004, 45:2 949-2 957.
  • 5Vrentas J S, Duda J L, Ling H C. Antiplasticization and Volumetric Behavior in Glassy Polymers[J]. Macromole- cules, 1988, 21 : 1 470- 1 475.
  • 6Suvorova A I, Hannanova E G. Molecular Structure of Plas- ticizers and Antiplasticization[J]. Die Makro. Chemie, 1990, 191:993-998.
  • 7Jones A A, Inglefield P T, Liu Y, et al. A Lattice Model for Dynamics in a Mixed Polymer-diluent Glass[J], J. Non-Cryst. Sol., 1991, 131-133:556-562.
  • 8Tiemblo E Martinez G, Gomez-Elvira J M, et al. On a Nov- el Interpretation of PVC Antiplasticization Based on Some Local Chain Conformations[J]. Polym. Bull., 1994, 32: 353-359.
  • 9Anderson S L, Grulke E A, DeLassus P T, et al. Model for Antiplasticization in Polystyrene[J]. Macromolecules, 1995, 28:2 944-2 954.
  • 10Soong S Y, Cohen R E, Boyce M C, et al. The Effects of Thermomechanical History and Strain Rate on Antiplastici- zation of PVC[J]. Polymer, 2008, 49:1 440-1 443.

同被引文献24

  • 1王发辉,张连红,梁红玉,于红艳,胡金友,敖文杰.MOCA的合成[J].化学与粘合,2007,29(2):92-94. 被引量：7
  • 2殷敬华 莫志深.现代高分子物理学[M].北京：科学出版社,2001.382-407.
  • 3付若文,李谷,冯开才.高分子物理[M].北京:化学工业出版社,2005:208-210
  • 4何曼君,张红东,陈维孝,等.高分子物理[M].3版.上海:复旦大学出版社,2006.
  • 5Song Yihu,Zheng Qiang.Application of Two Phase Model to Linear Dynamic Rheology of Filled Polymer Melts[J].Pol-ymer,2011,52:6173-6179.
  • 6Pattanayak A,Jana S C.Synthesis of Thermoplastic Polyurethane Nanocomposites of Reactive Nanoclay by Bulk Poly-merization Methods[J].Polymer,2005,46:3275-3288.
  • 7Kamal Musa R,Calderon Jorge Uribe,Lennox R Bruce.Surface Energy of Modified Nanoclays and Its Effect on Polymer/Clay Nanocomposites[J].J Adhes Sci Technol,2009,23:663-688.
  • 8Gao Lijun,Zhou Liming,Fang Shaoming,et al.New Poly(Urethane-methacrylate)s Obtained by Adjusting the Structureof the Polyols Moieties:Synthesis,Transparent,Thermal and Mechanical Properties[J].J Polym Res,2011,18(4):833-841.
  • 9于同隐.聚合物的黏弹性[M].上海:上海科学技术出版社,1986.
  • 10Dominique Langevin,Francisco Monroy.Interfacial Rheology of Polyelectrolytes and Polymer Monolayers at the Air-wa-ter Interface[J].Curr Opin Colloid Interface Sci,2010,15:283-293.

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Journal of Wuhan University of Technology(Materials Science)
2011年 第1期

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