摘要
报道了高分子显色剂聚乙烯醇缩对甲酰基苯偶氮变色酸(简称:PV·BCpF)做萃取剂时,Ni2+等常见过渡金属离子的非有机溶剂液-固萃取行为和影响萃取的各种因素,特别是对高分子显色剂的结构与分析性能的关系做了系统比较研究,并对萃取机理作了初步探讨。实现了Ni2+与常见过渡金属离子定量分离,分离系数Sf在6.0×102~5.0×103之间,常见离子不干扰。
n Tween 80inorganic salt water system the
liquidsolid extraction behavior of the complexes of nickel (II) with the polymeric chromogenic
reagent polyvinyl alcohol condensed pformylbenzenylazo chromotropic acid(PVBCpF) was
investigated . Under certain experimental conditions, nickel can be quantitatively separated
from other metals and the results of recovery are also satisfactory, the separation coefficient is
between 6.010250103. The proposed method has been applied to the determination of nickel in
aluminium alloys and environmental samples with satisfactory results.
出处
《分析试验室》
CAS
CSCD
1999年第3期11-14,共4页
Chinese Journal of Analysis Laboratory
基金
国家自然科学基金
关键词
镍
高分子显色剂
PV·BCpF
萃取剂
液固萃取
nickel
polyvinyl alcohol condensed pformylbenzenylazo chromotropic acid
liquidsolid extraction