摘要
研究了高氟代金属卟啉ＭｎＴＦＰＰＣｌ催化环己烯氧化反应的催化活性，探索了反应体系中不同单氧原子给体（ＰｈＩＯ、ＮａＯＣｌ、Ｈ２Ｏ２、ＭＣＰＢＡ）对催化反应的影响．结果表明，ＭｎＴＦＰＰＣｌ／ＮａＯＣｌ体系有较好的催化转移氧能力．主要以ＰｈＩＯ为氧化剂，考察了轴向配体。
In this paper the catalytic activity of metalloporphyrin
was studied. Influences of oxidant and axial ligand on cyclohexene oxidation catalyzed by this
catalyst were also investigated. The results indicated thatthe system of MnTFPPCl/NaOCl was
superior as compared to other systems. The effects of axial ligand were different for various
oxidants. In addition,the influence of solvent on the system of MnTFPPCl/PhIO was also
investigated.
出处
《分子催化》
EI
CAS
CSCD
北大核心
1999年第3期165-168,共4页
Journal of Molecular Catalysis(China)
关键词
高氟代
金属卟啉
锰卟啉
环己烯
氧化
催化剂
Tetrakis(pentafluorophenyl)porphyrin
Single oxygen atom donor
Axial
ligand
