摘要
用一维ＮＭＲ方法研究了新型电化学发光探针Ｒｕ（ｄｃｂｐｙ）（ｐｈｅｎ）２（ＰＦ６）２的立体结构，借助二维１Ｈ－１ＨＣＯＳＹ和１Ｈ－１３ＣＣＯＳＹ实验技术对其氢谱和碳谱进行了完全的归属，并给出了其氢谱和碳谱的化学位移值。
y using the
reaction of Ru(1,10phenanthroline)2Cl2 with 2,2bipyridine4,4dicarboxylic acid refluxed in
methanol and water,a new complex that has excellent property of electrochemiluminescence
was synthesized.The complex was characterized by means of NMRHowever,because of the
effect of Ru atom on ligands and steric configuration,it is difficult to attribute spectra of the title
molecule.By means of 2D1H1H COSY and1H13C COSY techniques,the NMR spectra are
assigned completely
出处
《分析试验室》
CAS
CSCD
1999年第4期14-17,共4页
Chinese Journal of Analysis Laboratory
基金
国家"九五"攻关重点项目
