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Co(En)_3MoO_4晶体的水热合成与表征 被引量:3

Hydrothermal Synthesis and Crystal Structure of Co(En)_3MoO_4
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摘要 Co(En)\-3MoO\-4 was synthesized by using the method of hydrothermal synthesis and characterized by elemental analysis, IR, ESR and single\|crystal X\|ray methods. It crystallizes in hexagonal space group \%P3C1\% with \{\%a\%=1\^596 4(2) nm\}, \{\%b\%=1\^596 4(2) nm\}, \%c\%=\{0\^993 5(2)\} nm, \%α=β\%=90°, \%γ\%=120°, \%M\%\-c=399\^18, \%V\%=2\^192 6(6) nm\+3, \%D\%\-c=1\^814 g/nm\+3, \%Z\%=6, \%F\%(000)=1 218, \%R\%\-1=0\^070 3, \%R\%\-w=0\^220 7. According to separation of anion which acted on electrostatic potential, the anion and cation ions formed a type of organic and inorganic material. Co(En)\-3MoO\-4 was synthesized by using the method of hydrothermal synthesis and characterized by elemental analysis, IR, ESR and single\|crystal X\|ray methods. It crystallizes in hexagonal space group \%P3C1\% with \{\%a\%=1\^596 4(2) nm\}, \{\%b\%=1\^596 4(2) nm\}, \%c\%=\{0\^993 5(2)\} nm, \%α=β\%=90°, \%γ\%=120°, \%M\%\-c=399\^18, \%V\%=2\^192 6(6) nm\+3, \%D\%\-c=1\^814 g/nm\+3, \%Z\%=6, \%F\%(000)=1 218, \%R\%\-1=0\^070 3, \%R\%\-w=0\^220 7. According to separation of anion which acted on electrostatic potential, the anion and cation ions formed a type of organic and inorganic material.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1999年第8期1186-1188,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金! (批准号 :2 9671 0 1 2 2 97330 90 )资助课题
关键词 杂多酸 Co(En)3MoO4 水热合成法 晶体 Hydrothermal synthesis, Crystal, \%P3C1\%
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