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聚β-羟基丁酸酯/超高分子量聚氧化乙烯共混体系相容性和结晶行为 被引量:10

MISCIBILITY AND CRYSTALLIZATION BEHAVIOR OF\=POLY(\|HYDROXYBUTYRATE)/POLY(ETHYLENE OXIDE) BLENDS
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摘要 为了解决废弃塑料引起的“白色污染”问题,世界各国竞相研制开发可生物降解高分子材料,其中,有关聚β羟基丁酸酯[poly(βhydroxybutyrate)(PHB)]的研究尤其活跃.然而,由于商品价格较高,材料本身抗冲击性能较差、加工窗口较窄等限制... The miscibility and crystallization behavior of poly(hydroxybutyrate)(PHB)/poly(ethylene oxide)(PEO)blends were studied by differential scanning calorimetry(DSC) and polarizing microscopy (POM).It is found that the miscibility is related to the composition of the blends.When the PEO content is over 20 percent,the miscible blends turn into partially miscible and the phase separation can be observed with POM.The addition of the PEO influences not only the morphology of PHB crystals and the radial growth rate of spherulites,but also the cold crystallization temperature.\=
出处 《高分子学报》 SCIE CAS CSCD 北大核心 1999年第4期498-501,共4页 Acta Polymerica Sinica
基金 国家自然科学基金
关键词 聚羟基丁酸酯 PHB PEO 共混物 Poly(\|hydroxybutyrate),Poly(ethylene oxide),Miscibility,Phase separation,Crystallization behavior,Spherulite growth
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