电解质溶液的不可逆过程热力学讨论

Discussion on Irreversible Thermodynamics of Electrolyte Solution

从不可逆过程热力学的耗散函数出发,推导了电解质溶液中阴、阳离子运动的方程式以及表征溶液导电性能的电导、迁移数、离子的迁移率和扩散系数等物理参数之间的关系.结果表明,从不可逆过程热力学理论得到的方程式与可逆过程热力学理论得到的相同.

The transfere quations of ions and the relations among the physical factors such as conductance,transference number,transference rate and diffusion coefficient of ions in electrolyte solutions was educed by means of nonequilibrium thermodynamics.The results show that the equations from nonequilibrium thermodynamics are consistent with that from classical thermodynamics.