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Preparation of CuS-P(NIPAM-co-MAA) Hybrid Microgels with Controlled Surface Structures

Preparation of CuS-P(NIPAM-co-MAA) Hybrid Microgels with Controlled Surface Structures
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摘要 Copper sulfide-poly(isopropylacrylamide-co-methacrylic acid) [CuS-P(NIPAM-co-MAA)] hybrid microgels with patterned surface structures have been synthesized by means of the polymer microgel template technique. The results showed that the surface morphology of the hybrid microgels could be regulated by controlling the decomposition of thioacetamide (TAA) in an acidic medium. The rate of precipitation and the amount of metal sulfide significantly affect the surface structures of the hybrid microgels. Copper sulfide-poly(isopropylacrylamide-co-methacrylic acid) [CuS-P(NIPAM-co-MAA)] hybrid microgels with patterned surface structures have been synthesized by means of the polymer microgel template technique. The results showed that the surface morphology of the hybrid microgels could be regulated by controlling the decomposition of thioacetamide (TAA) in an acidic medium. The rate of precipitation and the amount of metal sulfide significantly affect the surface structures of the hybrid microgels.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2011年第1期33-40,共8页 中国化学(英文版)
基金 Project supported by the National Natural Sciences Foundation of China (No. 20373039), and the Natural Science Foundation of Shaanxi Province of China (No. 2007Ej06)
关键词 polymer microgels templates metal sulfides organic-inorganic hybrid composite polymer microgels, templates, metal sulfides, organic-inorganic hybrid composite
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