摘要
硼 trifluoride 导致了 aryltriazenes 的 Suzuki-Miyaura 跨 coupling, arylboronic 酸由 Pd (OAc ) 催化没有增加的 ligands, 2 第一次被完成了。在氩气氛下面在房间温度执行的反应交上 biaryls 对优秀收益好。反应在温和、 ligand 免费的条件下面被进行,是引人注目的。
The boron trifluoride induced Suzuki-Miyaura cross-coupling of aryltriazenes with arylboronic acids catalyzed by Pd(OAc)2 without added ligands has been achieved for the first time. The reactions performed at room temperature under an argon atmosphere give biaryls in good to excellent yields. It is noteworthy that the reactions were conducted under mild and ligand-free conditions.