摘要
The reaction of 4-amino-3,5-bis（imidazol-l-ylmethyl）-1,2,4-triazole （abit） and manganese（Ⅱ） salts yields four coordination polymers {[Mn（abit）3]（C104）z}n （1）, {[Mn（abit）3]（PF6）2},, （2）, [Mn（abit）（dca）2（H2O）2],, （3a） and [Mn（abit）（dca）2（H2O）2]n （3b）. Compounds 1 and 2 are one-dimensional triple-stranded chain. Compounds 3a and 3b are polymorphous and construct one-dimensional single chain. The conformational analysis is performed. The thermal properties have been investigated.
The reaction of 4-amino-3,5-bis（imidazol-l-ylmethyl）-1,2,4-triazole （abit） and manganese（Ⅱ） salts yields four coordination polymers {[Mn（abit）3]（C104）z}n （1）, {[Mn（abit）3]（PF6）2},, （2）, [Mn（abit）（dca）2（H2O）2],, （3a） and [Mn（abit）（dca）2（H2O）2]n （3b）. Compounds 1 and 2 are one-dimensional triple-stranded chain. Compounds 3a and 3b are polymorphous and construct one-dimensional single chain. The conformational analysis is performed. The thermal properties have been investigated.
基金
Project supported by the National Natural Science Foundation of China （No. 20671066）, the Jiangsu Province （No. BK2006049）, and the Funds of Key Laboratory of Organic Synthesis of Jiangsu Province.
