聚合物纳米杂化材料的控制合成、自组装及功能化

Controlled synthesis,self-assembly,and funtionalization of polymer nano-hydrid materials

聚合物纳米杂化材料的制备及功能化是当前国际前沿研究课题之一.特殊结构的聚合物可以通过分子间特殊相互作用,在纳米尺度上自发地组装成具有特殊结构和形态的集合体,这类材料在新材料、电子以及生物医学等领域具有广泛的应用前景.本文介绍国内外,特别是厦门大学在双亲性分子及嵌段共聚物的模板自组装、基于POSS单体纳米构筑单元以及POSS嵌段聚合物自组装的有机/无机纳米杂化材料、模板控制导电高分子材料纳米形态构筑等领域材料的可控合成和组装,与此同时对相关材料的性能及功能化应用进行了简要的讨论.

The synthesis and functionalization of polymer based nano-hybrid materials is one of the hottest fields all over the world.Polymers with specific structures can interact distinguishingly with each other by special intermolecular interactions,which induce them self-assemble into aggregations possessing special structures and morphologies.These structures exhibit great potential applications in many fields such as new materials,electronics and biomedicines.This review introduced the research progress in these fields of China and abroad,especially Xiamen University.The content mainly included the template associated self-assembly of amphiphilic molecules;the organic/inorganic hybrid materials based on POSS monomer nano building blocks and POSS block polymers self-assembly and template controlling construction of conduct ive polymeric nano-structure.Besides introducing the controllable synthesis and self-assembly of relative materials,this paper also discusses the properties and functionalization of the nano-materials,briefly.