期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

钙硼硅系玻璃陶瓷低温烧结研究 被引量：1

Research on Low-temperature Sintered of CaO-B_2O_3-SiO_2 Glass-ceramics
下载PDF
导出
摘要 利用不同粒度的CaO-B2O3-SiO2(CBS)玻璃粉料,制备了低温烧结的CBS玻璃陶瓷。研究了粉料粒度对CBS系玻璃陶瓷低温烧结的影响。实验表明,粉料粒度对粉料的玻璃化温度Tg的影响不明显,玻璃致密化开始于玻璃化温度Tg≈680℃,随着烧成温度升高,收缩率迅速增大;随着粉料粒度的减小,试样的烧结温度和显气孔率降低,体积密度、收缩率、热膨胀系数和抗折强度都增大。将粉料粒径中位值D50=2.34μm的粉料采用流延工艺制得127μm的生料带,运用优化烧成工艺,与银电极浆料在850℃共烧,表面平整,匹配良好,能在一定程度上满足低温共烧陶瓷(LTCC)用基板材料的要求。 The CaO-B2O3-SiO2（CBS） glass-ceramics were prepared by the powders of different grain sizes.The effect of the grain size of glass powder on the sintering behavior of the glass ceramics was investigated.The experimemtal results showed that the grain size of the glass powder had no significant effect on the glass transition temperature Tg.The glass-ceramics started to densify at about Tg≈680 ℃,then shrinking enlarged rapidly with the sintering temperature increasing.By reducing the grain size of glass powders,the sintered temperature and the apparent porosity decreased,while the bulk density,the shrinkage ratio,the thermal expansivity and the fracture strength increased.By using the casting process,the green tape of 127 μm has been prepared with the powders of grain size D50=2.34 μm.Then it was co-fired with the Ag electrode paste at 850 ℃ by using the optimized firing technology.The obtained CBS glass-ceramics system had no camber and mismatch,which could satisfy with the requirements of the substrate materials used in LTCC.
作者 韦鹏飞 周洪庆 朱海奎 王杰 曾凤 吴路燕
机构地区 南京工业大学材料科学与工程学院
出处 《压电与声光》 CSCD 北大核心 2011年第2期268-271,共4页 Piezoelectrics & Acoustooptics
基金 国家高技术研究发展计划("八六三"计划)基金资助项目(2007AA03Z0455) 江苏省产学研科技支撑基金资助项目(BE2009168)
关键词 钙硼硅 低温共烧 银电极浆料 性能 CaO-B2O3-SiO2（CBS） low temperature co-fired Ag electrode paste properties
分类号 TN305 [电子电信—物理电子学] TB34 [一般工业技术—材料科学与工程]
  • 相关文献

参考文献12

  • 1ZUO Ruzhong, LI I.ongtu, I;UI Zhilun. Interfacial development and micro-structural imperfection of rnul-tilayer ceramic chips with Ag/Pd electrodes [J]. Ceramics International, 200J (27): 889-893.
  • 2CHANG C R, JEAN J H. Crystaliization kinetics and dielectric properties of CaO B, O3-SiO2 system glass ceramics[J]. Am Ceram Soc, 1999(82) :1725-1732.
  • 3JEAN J H, CHANG C 12, I.EI C D. Sintering of a crystallizable OaOB2 O3-SiO:z glass with silver [J]. J Am Ceram Soc,2004(74) : 1244-1249.
  • 4HARTMANN H S. Crystallizable, low dielectric con- stant, low dielectric loss composition[P]. U. S. Patent: No. 5024, 975,1991-6-18.
  • 5WANG S H, ZHOU H P, Densification and dielectric properties of CaOB,eOa system glass ceramics[J]. Mater Sci Eng B,2003,99(1 3): 597 600.
  • 6SHAPIRO A A. Process-structure-property relation ships in recrystallizing calcium oxide boron oxide-sili con dioxide[J]. Irvine, U. S. A : University of Califor nia, 1998.
  • 7MURALIDHAR S K, SHAIKH A S, ROBERTS G J, et al. Low dielectric, low temperature fired glass- ceramics[P]. U.S. Patent:No. 5164342,1992 11-17.
  • 8JEAN J H,CHANG C R. Camber development during co-firing Ag-based low-dielectric-constant ceramic packaging[J]. J Mater Res Soc, 1997,12(10):2743- 2750.
  • 9CHUNG L L, DUH J G. Low temperature sintering and crystallization behavior of low loss anorthite-basedglass ceramies[J]. J Mater Sei, 2003, 38: 693-698.
  • 10KINGERY W D, BOWEN H K, UHLMANN D R. Introduction to eeramies[M]. .New York: Wiley Sons, 1976.

二级参考文献14

  • 1XIAN Young, XIE Daohua. New technology for multilayer chip component[J]. Electronic Components & Materials, 1999(18) : 34-40.
  • 2HSU J Y, I.IN H C, SHEN H D, et al. High frequency multilayer chip inductors[J]. IEEE Transactions on Magnetics, 1997, 33(5): 3325-3327.
  • 3JEAN J H, CHANG C R, LEI C D. Sintering of a crystallizable CaO-B2O3-SiO2 glass with silver [J]. J Am Ceram Soc, 2004(71): 1244-1249.
  • 4HANMANN H S. Crvstallizable low dielectric constant, low dielectric, loss composition [P]. U. S. Patent: No. 5024975,1991.
  • 5WANG Shaohong, ZHOU Heping. Densification and dielectric properties of CaO-B2O3-SiO2 system glass ceramics Mater[J]. Mater Sci Eng B, 2003(99) : 597- 600.
  • 6CHUNG LL, LUN L, JENQ G D, et al. Low temperature sintering and crystallization behavior of low loss anorthite-based glass-ceramics[J]. J Mater Sci, 2003(38): 693-698.
  • 7CHENCS, CHOUCC, CHENCSH, etal. Micro- wave dielectric properties of glass-MCT low temperature co-firable ceramics[J]. J Eur Ceram Soc, 2004 (24) : 1795-1798.
  • 8KINGERY W D, BOWEN H K, UHLMANN D R. Introduction to Ceramies[M]. New York: John Wiley & Sons, 1976.
  • 9CHANG C R, JEAN J H. Crystallization kinetics and mechanism of low-dielectric, low-temperature, cofirable CaO-B2O3-SiO2 glass-ceramics [J]. J Am Ceram Soc, 1996(82): 1725-1732.
  • 10TUMMALA R R, KNICKERBOCKER J U, KNICKERBOCKER S H, et al. High-performance glass-ceramic/copper multilayer substrate with thin film redis tribution[J]. J Res Develop, 1992, 36(5): 889-904.

共引文献3

同被引文献11

  • 1杨娟,堵永国,张为军,周文渊.低温共烧基板材料研究进展[J].材料导报,2006,20(10):12-16. 被引量：16
  • 2MOHANRAM A, MESSING G L, GREEN D J. Densification and sintering viscosity of low-temperature co-fired ceramics [J]. J Am Ceram Soc, 2005, 88: 2681-2689.
  • 3YOON S O, KIM K S, KIM S, et aL Densification dielectric properties of glass/ceramic sintered with various borosilicate glass [J]. Mater Sei Forum, 2007, 544/545:961-964.
  • 4RAY A, TIWARI A N. Compaction and sintering behavior of glass-alumina composites [J]. Mater Chem Phys, 2001,67(1): 220-225.
  • 5JUNG B H, H WANG S J, KIM H S. Application of La203-B203-TiO2 glass-ceramic for low temperature co-fired ceramic (LTCC) materials [J]. Mater Sci Forum, 2004, 449/450/451/452: 729-732.
  • 6SIMS H, KANG C Y, CHO1 J W, et al. A compact lumped-element Iowpass filter using low temperature co-fired ceramic technology [J]. J Eur Ceram Soc, 2003, 23(14): 2717-2720.
  • 7ZHANG Q L,YANG H, ZOU J L, et al. Sintering and microware dielectric properties of LTCC-zine titanate multilayers [J]. Mater Lett, 2005, 59: 880-884.
  • 8CHUNG L L, LUN L, JENQ G D, et al. Low temperature sintering and crystallization behavior of low loss anorthite-based glass-crramics [J]. J Mater Sei, 2003, 38: 693-698.
  • 9陈兴宇,张为军,堵永国,郑晓慧.硼硅酸盐玻璃/氧化铝低温共烧陶瓷材料的烧结[J].电子元件与材料,2009,28(1):8-10. 被引量：7
  • 10毛兴龙,周洪庆,赵建新,曾凤,朱海奎.烧结温度对硼硅酸盐玻璃/氧化铝复相陶瓷性能的影响[J].电子元件与材料,2012,31(10):9-11. 被引量：3

引证文献1

二级引证文献1

压电与声光
2011年 第2期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部