二氧化氯物理化学性质研究进展

A Review on Study State and Progress of Chlorine Dioxide Physichemical Property

主要介绍了新型消毒剂ＣｌＯ２的物理化学性质，结合我们的一些研究成果和国内外研究动态做了较全面的综合评述。除介绍了ＣｌＯ２的一般物理化学性质外，还介绍了ＣｌＯ２气相和液相的光解反应，涉及的研究方法有ＵＶ和ＩＲ吸收光谱，电子自族共振谱（ＥＳＲ），拉曼光谱，强共振多光子电离谱（ＲＥＭＰＩ）和从头算量化法以及相关理论。了解ＣｌＯ２的这些物理化学性质为它的应用和理论研究提供了依据。

This paper introduced the present study state of chlorine dioxide physichemical properties.Photodissociation and some important research methods have been also introduced. The photodissociation ofClO2 gas - phase and liquid -- phase and its study either by UV and IR absorption spectrum, electro spinresonance(ESR). Laman spectrum or resonance - enhanced multiphoton inization(REMPI) as well as therelated theory, such as molecular orbit theory, are put forward. This paper provides a basis for theoretical studyand application of chlorine dioxide.