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化合物[{(NCHCHNCH_3)CH}_3] Li Cl的合成与晶体结构

Synthesis and Crystal Structureof [{(NCHCHNCH_3)CH}_3] LiCl
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摘要 甲基咪唑与氯化锂反应成功地合成了[{(NCHCHNCH3)CH}3LiCl]。化合物通过了元素分析,核磁和x-ray衍射表征。晶体结构表明其晶体属单斜晶系,空间群为C c,化学式为C12H18N6ClLi,晶胞参数为a=13.556(4)A°,b=9.061(3)A°C=12.287(4)A°,α(deg)=90 deg,β(deg)=93.671(6)deg,γ(deg)=90 deg,V(A°3)=1506.2(8)A°3,Z=4,最终R1=0.058,wR2=0.149. The reaction of LiCl with CH（MeNCHCHNH）} in a ratio of 1：3 gives the compound [{CH（MeNCHCHNH）}]3LiCl,The compound I has been characterized by the 1HNMR,elementary analysis and X-ray diffraction.The result shows that the crystal belongs to triclinic system.And the Empirical formula is C12H18 N6ClLi,a=13.556（4）A.,b=9.061（3） A.C=12.287（4）A.,α（deg）=90 deg,β（deg）=93.671（6）deg,γ（deg）=90 deg,V（A.3）=1506.2（8）A.3,Z=4,R1=0.058,wR2=0.149.
作者 王志国 李红波 刘婷 刘思曼 邓毅
机构地区 绵阳师范学院化学与化学工程学院
出处 《绵阳师范学院学报》 2011年第2期38-43,共6页 Journal of Mianyang Teachers＇ College
基金 四川省应用基础基金资助项目(2009JY0075) 绵阳师范学院学生科研(hx2010-2011-15)
关键词 咪唑 氯化锂 合成 结构 imidazole lithium chloride synthesis structure
分类号 O626 [理学—有机化学]
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参考文献11

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绵阳师范学院学报
2011年 第2期

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