摘要
Two new polyoxomolybdate compounds,namely（CuIIL2）2[CuⅡ（HL）2]2[Mo8O26（HL）2].（H2O）4（1） and [CuⅡ（HL）2]2[β-Mo8O26]（HL）2（2）（HL=imidazole）,were designed and synthesized under hydrothermal conditions.X-ray diffraction analyses reveal that compound 1 consists of one Mo8O26（HL）24-cluster,two CuL2,two Cu（HL）22＋,and four disassociated water molecules;and compound 2 is constructed by one β-Mo8O264-cluster,two Cu（HL）22＋,and two uncoordinated imidazole molecules.
Two new polyoxomolybdate compounds,namely（CuIIL2）2[CuⅡ（HL）2]2[Mo8O26（HL）2].（H2O）4（1） and [CuⅡ（HL）2]2[β-Mo8O26]（HL）2（2）（HL=imidazole）,were designed and synthesized under hydrothermal conditions.X-ray diffraction analyses reveal that compound 1 consists of one Mo8O26（HL）24-cluster,two CuL2,two Cu（HL）22＋,and four disassociated water molecules;and compound 2 is constructed by one β-Mo8O264-cluster,two Cu（HL）22＋,and two uncoordinated imidazole molecules.
基金
supported by Financial support from the Natural Science Foundation of Shandong Province (BR2010BQ023)
Shandong Provincial Education Department,and Qilu Normal University
