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锂离子电池5V正极材料LiCoPO_4/C的合成与性能 被引量:1

Synthesis and Performance of LiCoPO_4/C as 5 V Cathode Material for Lithium Ion Batteries
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摘要 采用高温固相法合成锂离子电池用LiCoPO4/C复合正极材料.通过X射线衍射(XRD)和扫描电镜(SEM)对材料的微观结构和表面形貌进行分析.电化学测试结果表明,在0.1 C倍率下,LiCoPO4/C首次放电容量达到75 mAh.g-1,50次循环容量保持92%. The LiCoPO4 /C composite cathode material was synthesized by high-temperature solid-state reaction.Micostructure and morphology of the samples were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM).The electrochemical tests showed that the initial discharge capacity of LiCoPO4/C reached 75 mAh·g^-1 and 92% capacity retention was obtained after 50 cycles at 0.1 C rate.
出处 《淮北师范大学学报(自然科学版)》 CAS 2011年第1期50-52,共3页 Journal of Huaibei Normal University:Natural Sciences
基金 安徽省高校青年教师资助计划项目(2007jql156) 安徽高校省级自然科学研究项目(KJ2009B250Z) 淮北师范大学青年科研项目(201132)
关键词 锂离子电池 磷酸钴锂 正极材料 高电压 lithium ion batteries lithium cobalt phosphate cathode material high-voltage
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参考文献6

  • 1OSORIO-GUILLEN J M,HOLM B,AHUJA R,et al.A theoretical study of olivine LiMPO4 cathodes?[].Solid State Ionics.2004
  • 2BORGEL V,MARKEVICH E,AURBACH D,et al.On the application of ionic liquids for rechargeable Li batteries:High voltagesystems[].Journal of Power Sources.2009
  • 3HAN D W,KANG Y M,YIN R Z,et al.Effects of Fe doping on the electrochemical performance of LiCoPO4/C composites forhigh power-density cathode materials[].Electrochemistry.2009
  • 4Ceder G,Chiang Y M,Sadoway D R,et al.Identification of cathode materials for lithium batteries guided by first-principles calculations[].Nature.1998
  • 5H.H.Li,J.Jin,J.P.Wei,et al.Fast synthesis of core-shell Li-CoPO4/C nanocomposite via microwave heating and its electro-chemicalLiintercalationperformances[].ElectrochemistryCom-munications.2009
  • 6Andersson A M,Abraham D P,Haasch R, et al.Surface Characterization of Electrodes from High Power Lithium-Ion Batteries[].Journal of the Electrochemical Society.2002

同被引文献21

  • 1Zhao, Yujuan, Wang, Suijun, Zhao, Chunsong, Xia, Dingguo.Synthesis and electrochemical performance of LiCoPO_4 micron-rods by dispersant-aided hydrothermal method for lithium ion batteries[J].Rare Metals,2009,28(2):117-121. 被引量:11
  • 2Hua Ju, Jun Wu,Yanhui Xu. Lithium ion intercalation mechanism for LiCoPO4 electrode [J]. International Journal of Energy and Environmental Engineering, 2013,4:22.
  • 3Bramnik NN, Bramnik KG, Baehtz C, et al. Study of the effect ofdifferent synthesis routes on Li extraction - insertion from LiCoPO [J]. J Power Sources, 2005, 145:74--81.
  • 4Kishore MVVMS, Varadaraju UV. Influence of isovalention substitution on the electrochemical performance of LiCoPO4 [J]. Mater Res Bull, 2005,40 .. 1705 -- 1712.
  • 5Yamada, A, Chung SC. Crystal chemistry of the oli- vine-type Li ( MnyFel-y ) PO4 and ( MnyFel-y ) PO4as possible 4V cathode materials for lithium batteries[J]. J Eleetrochem Soc, 2001,148 : A960-- A967.
  • 6Ruffo R, Mari CM, Morazzoni F, et al. Electrical and electrochemical behaviour of several LiFexCol-PO4 sol- id solutions as cathode materials for lithium ion batteries [J]. Ionics,2007,13:287--291.
  • 7Natalia N Bramnik, Kirill G Bramnik, Carsten Baehtz, et al. Study of the effect of different synthesis routes on Li extraction - insertion from LiCoPO4 [J]. Journal of Power Sources , 2005,145 : 74-- 81.
  • 8Jun Yoshida , Shinji Nakanishi, Hideki Iba. Improve- ment of battery performances of LiCoPO4 as cathode material for lithium Ion Batteries[C]// Abstract 796, The Electrochemical Society Meeting Abstracts. Hon- olulu, HI. The Electrochemical Society,2012.
  • 9Masashi Kotohuki. Hydrothermal synthesis of carbon- coated LiCoPO4 EJJ- International Journal of Energy and Environmental Engineering, 2013(4) : 25.
  • 10Wolfenstine J, Read J, Allen J L. Effect of carbon on the electronic conductivity and discharge capacity LiCo- PO4 [J]. Journal of Power Sources, 2007,163 : 1070- 1073.

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