期刊文献+

二烯醇硅醚在芳环及芳杂环合成中的研究进展

Advances of 1,3-Bis (Silyl Enol Ethers) in Aromatic and Heterocyclic Synthesis
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摘要 二烯醇硅醚是一类非常重要的有机合成中间体,能通过环化反应合成各种重要的药理活性化合物,这些化合物不易通过其他方法制备。文章对二烯醇硅醚在有机合成中的研究进展进行了综述。 1,3-Bis(silyl enol ethers) were of considerable intermediates in organic synthesis,they can be used to synthesize various pharmacological active compounds by cyclization reactions,which are not readily available by other methods.In the paper,1,3-bis(Silyl enol ethers) in organic synthesis of the research were reviewed.
出处 《广东化工》 CAS 2011年第4期9-11,共3页 Guangdong Chemical Industry
基金 国家自然科学基金(30860342) 云南省自然科学基金(2009CC017 2008CD063)资助项目
关键词 二烯醇硅醚 环化反应 综述 1 3-bis(silyl enol ethers) cyclization review
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参考文献27

  • 1Langer P. Recent advances in organosilicon chemistD, directed towards organic synthesis Foreword[J]. Tetrahedron, 2009, 65: 5545.
  • 2Hussain 1, Yawer M A, Langer P, et al. Regioselective Synthesis of Fluorinated Phenols, Biaryls, 6H-Benzo[c]chromen-6-ones and Fluorenones Based on Formal [3+3] Cyclizations of 1,3-Bis(sily[ enol ethers)[J]. Eur J Org Chem , 2008: 503-518.
  • 3Langer P. One-Pot Synthesis of Functionalized 3-(Trifluoromethyl)phenols by [3+3] Cyclization of 1,3-Bis(silyl enol ethers) with α,β-Unsaturated Trifluoromethyl Ketones[J]. Eur J Org Chem, 2008: 492-502.
  • 4Langer P. Synthesis of Fluorinated Arenes and l-tetarenes Based on One-Pot Cyclizations of 1,3-Bis(trimethylsilyloxy)-l,3-butadienes[J]. Synlett, 2009, 14: 2205-2216.
  • 5Buttner S, Lubbe M, Reinke H, et al. Regioselective synthesis of 4-alkyl- and 4-aryl-6- (perlluoroalkyl)salicylic acid derivatives by formal [3+3] cyclocondensation of 1,3-bis(silyloxy)- 1,3-butadienes with 3-silyloxy-l-(perlluoroalkyl) prop-2-en-1-ones[J]. Tetrahedron, 2008, 64: 7968-7976.
  • 6Reim S, Langer P. The first 4-chloro-l,3-bis(trimethylsilyloxy)-l,3-diene and its application to the regioselective synthesis of chlorinated arenes[J]. TetrahedronLett, 2008, 49: 2329-2332.
  • 7Wolf V, Adeel M, Reim S, et al. Diversity-Oriented Synthesis of Chlorinated Arenes by One-Pot Cyclizations of 4-Chloro-1.3-bis(trimethylsilyloxy) buta- 1,3-dienes[J]. Eur J Org Chem, 2009 : 5854-5854.
  • 8Abid O U R, lbad M F, Nawaz M, ct a[. Synthesis of 3,5 -diaryl-4-chlorophthalates by [4+2] cycloaddition of l-ethoxy-2-chloro- 1,3-bis(trimethylsilyloxy)- 1,3-diene with dimethyl acetylene dicarboxylate and subsequent site-selective Suzuki--Miyaura reactions[J]. TetrahcdronLett, 2010, 51: 657-660.
  • 9Reim S, Adeel M, Hussain I, et al. Synthesis and reactions of 2-chloro- 1,3-bis (trimethylsilyloxy)- 1,3-butadienes[J]. Tetrahedron Lett, 2008, 49 : 4901-4904.
  • 10Karapetyan V, Mkrtchyan S, Ghazaryan G, et at. Synthesis of dichloromethyl-substituted salicylates and pyran-4-ones by cyclocondensation of 1,3-bis(silyloxy)- 1,3-butadienes with 1, l-dimethoxy-4,4- dichlorobut-l-en-3-one: control of the C,C- and C,O-rcgioselectivity by the choice ofLewisacid[J]. Tetrahedron, 2009: 1-7.

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