Meso位直结型稳定双卟啉的合成及性质

HIGH YIELD SYNTHESIS ROUTE FOR DIRECTLY MESO LINKED PORPHYRIN DIMERS AND THEIR PROPERTIES

利用氧化法成功地合成了同核 ｍｅｓｏ 位直结型稳定卟啉二聚体锌络合物，收率接近理论值；无论是碱式还是金属络合物都显示出卟啉环间成平面正交的电子吸收光谱；在循环伏安图谱中都显示出卟啉环间再氧化还原过程中较强烈的库仑作用；每个卟啉环的一电子氧化或还原均为可逆过程．

One synthesis route for metal complexes of directly meso linked porphyrin dimer in a nearly quantitatively yield was developed. The dimerization was achieved via chemical oxidation. The metal complexes of the dimer exhibit absorption spectra that reveal the two porphyrin rings are in an orthogonal structure; cyclic voltamogramm confirmed the dimers are relatively stable in electrochemical process; strong Coulomb interaction is observed during the electrochemical process.