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Ultrasonic Study of Basic αr-Amino Acids in Different Acetate Salt Solutions at Different Temperatures 被引量:1

Ultrasonic Study of Basic a-Amino Acids in Different Acetate Salt Solutions at Different Temperatures
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摘要 The ultrasonic velocity (U), has been measured for three a-amino acids, namely L-lysine monohydrochloride, L-arginine and L-histidine in solutions (1 mol/L aqueous) of sodium acetate (SA), potassium acetate (PA) and calcium acetate (CA) at different temperatures (303.15, 308.15, 313.15, 318.15 and 323.15 K). With the help of these results various ultrasonic derived parameters, viz. isentropic compressibility (Ks), change in isentropic compressibility (△K5), relative change in isentropic compressibility (△Kr), specific acoustic impedance (Z), relative association (RA), and apparent molal compressibility (Фks) have been estimated. The results have been interpreted in the light of intermolecular interactions between solute and solvent. The ultrasonic velocity (U), has been measured for three a-amino acids, namely L-lysine monohydrochloride, L-arginine and L-histidine in solutions (1 mol/L aqueous) of sodium acetate (SA), potassium acetate (PA) and calcium acetate (CA) at different temperatures (303.15, 308.15, 313.15, 318.15 and 323.15 K). With the help of these results various ultrasonic derived parameters, viz. isentropic compressibility (Ks), change in isentropic compressibility (△K5), relative change in isentropic compressibility (△Kr), specific acoustic impedance (Z), relative association (RA), and apparent molal compressibility (Фks) have been estimated. The results have been interpreted in the light of intermolecular interactions between solute and solvent.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2011年第4期669-678,共10页 中国化学(英文版)
关键词 ultrasonic velocity (U) amino acid salt effect isentropic compressibility organic salt ultrasonic velocity (U), amino acid, salt effect, isentropic compressibility, organic salt
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