摘要
MgAl and MgMAl oxides(M = Co,Ni and Cu) with a Mg:M:Al molar ratio = 4:1:1 were synthesized from the calcination of their corresponding layered double hydroxide(LDHs) precursors.Their catalytic activities were examined for the oxidation of ethylbenzene using tert-butylhydroperoxide(TBHP) as an oxidant.The oxidized product was mainly acetophenone.The catalytic activities were in the order of MgCuAlMgNiAl~NiAl~MgCoAl~CoAlCuAlMgAl oxides.Reusability studies show that the catalysts are stable under the reaction conditions.
MgAl and MgMAl oxides(M = Co,Ni and Cu) with a Mg:M:Al molar ratio = 4:1:1 were synthesized from the calcination of their corresponding layered double hydroxide(LDHs) precursors.Their catalytic activities were examined for the oxidation of ethylbenzene using tert-butylhydroperoxide(TBHP) as an oxidant.The oxidized product was mainly acetophenone.The catalytic activities were in the order of MgCuAlMgNiAl~NiAl~MgCoAl~CoAlCuAlMgAl oxides.Reusability studies show that the catalysts are stable under the reaction conditions.
基金
support from the research grant"The 90th Anniversary of Chulalongkorn University Fund" from the Graduate School,Chulalongkorn University