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A V-shaped spectroscopic cell for FTIR measurements

A V-shaped spectroscopic cell for FTIR measurements
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摘要 A V-shaped spacroscopic cell(V-cell) was constructed using two CaF2 optical plates for FTIR light transparent measurements in the range of 4000-1000 cm^(-1).The spectrum of ethanol was characterized with the standard spectra,excellent fitting was achieved with a bottom-width correction method.The principle of the V-cell was discussed,giving equations for the data interpretation.It shows that the V-cell is an auto-focus type spectroscopic cell,which can effectively avoid absorption saturation with amplifications for weak absorption bands.The V-cell design is simple and effective,easy to operate,suitable for applications in liquid samples with high absorption bands,willing to have broad application prospects. A V-shaped spacroscopic cell(V-cell) was constructed using two CaF2 optical plates for FTIR light transparent measurements in the range of 4000-1000 cm^(-1).The spectrum of ethanol was characterized with the standard spectra,excellent fitting was achieved with a bottom-width correction method.The principle of the V-cell was discussed,giving equations for the data interpretation.It shows that the V-cell is an auto-focus type spectroscopic cell,which can effectively avoid absorption saturation with amplifications for weak absorption bands.The V-cell design is simple and effective,easy to operate,suitable for applications in liquid samples with high absorption bands,willing to have broad application prospects.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2011年第4期481-484,共4页 中国化学快报(英文版)
关键词 V-shaped cell FTIR spectroscopy Light transparent Error correction Demountable ETHANOL V-shaped cell FTIR spectroscopy Light transparent Error correction Demountable Ethanol
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参考文献4

  • 1C.W. Robertson, D. Williams, J. Opt. Soc. Am. 61 (1971) 1316.
  • 2I.L. Tyler, G. Taylor, M.R. Querry, Appl. Opt. 17 (1978) 960.
  • 3D.M. Wieliczka, S.S. Weng, M.R. Querry, Appl. Opt. 28 (1989) 1714.
  • 4X.Q. Lin, K.M. Kadish, Proc. 2nd Conf. and Exhib. on Instrum. Analysis, Beijing, (1987), p. 1311.

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