摘要
Supramolecular structures formed by H4TPPS42-have been widely used for different applications.In this paper,the stability of H4TPPS42? nanorods on mica substrate is investigated by atom force microscopy (AFM) observation.An irreversible transformation of H4TPPS42-from nanorods (3.8±0.4 nm in height) to a lower film structure (1.9±0.4 nm in height) was found with the samples incubated at various relative humidities (RH).The transformation rate depends strongly on the RH and environment temperature.
Supramolecular structures formed by H4TPPS42-have been widely used for different applications.In this paper,the stability of H4TPPS42- nanorods on mica substrate is investigated by atom force microscopy （AFM） observation.An irreversible transformation of H4TPPS42-from nanorods （3.8±0.4 nm in height） to a lower film structure （1.9±0.4 nm in height） was found with the samples incubated at various relative humidities （RH）.The transformation rate depends strongly on the RH and environment temperature.
基金
Supported by grants from Chinese Academy of Sciences (No. KJCX2.YW.H06 and No. KJCX2.YW.M03)
the National Science Foundation of China (No. 10975175 and No. 90923002)
the National Basic Research Program of China (No. 2007CB936000)
the Ministry of Health of China (2009ZX10004-301)
the Shanghai Municipal Commission for Science and Technology (0952 nm04600)
