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Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride 被引量:2

Preparation of Thin Film Composite Nanofiltration Membrane by Interfacial Polymerization with 3,5-Diaminobenzoylpiperazine and Trimesoyl Chloride
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摘要 新芳香的肼, 3,5-diaminobenzoylpiperazine (3,5-DABP ) ,从 3,5-diaminobenzoic 酸和 1 甲酰 piperazine 被综合。3,5-DABP 的结构被英尺红外系列和 1H NMR 系列识别。与是的 3,5-DABP 水的单体和 trimesoyl 氯化物(TMC ) 作为器官的单体,薄电影合成(TFC ) nanofiltration 膜被界面的聚合技术准备。这些 TFC 膜的盐拒绝顺序是 Na2SO4 > MgSO4 > MgCl2 > NaCl。这个序列显示膜否定地被控告。 A new aromatic diamine,3,5-diaminobenzoylpiperazine (3,5-DABP),was synthesized from 3,5-diaminobenzoic acid and 1-formyl piperazine.The structure of 3,5-DABP was identified by FT-IR spectra and 1H NMR spectra.With 3,5-DABP as aqueous monomer and trimesoyl chloride (TMC) as organic monomer,thin film composite (TFC) nanofiltration membranes were prepared by interfacial polymerization technology.The salt rejection order of these TFC membranes is Na2SO4MgSO4MgCl2NaCl.This sequence indicates that the membranes are negatively charged.
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第2期262-266,共5页 中国化学工程学报(英文版)
基金 Supported by the National Natural Science Foundation of China(21076176) the Research and Development Project of Tangshan(10140201C-3) the Research and Development Project of Hebei Province(07275113) the Research Fund of Tangshan Normal College
关键词 复合纳滤膜 有机氯化物 界面聚合 膜制备 薄膜 核磁共振光谱 氨基苯甲酸 芳香二胺 thin film composite membrane 3 5-diaminobenzoylpiperazine trimesoyl chloride interfacial polymerization
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