一个新的粘液酸锰(Ⅱ)配合物的合成、结构与性能研究(英文)

Synthesis,Crystal Structure and Properties of a New Manganese(Ⅱ) Complex with Mucic Acid

合成了1个以粘液酸为配体的锰(Ⅱ)配合物Mn[(muc)(H2O)3].H2O(1),并通过红外光谱,元素分析,热重分析和X-射线单晶衍射对其进行了表征。配合物1由一维链组成,其三维网络结构可以简化为dia拓扑。初步的电化学实验表明,配合物1在电化学储能上有应用潜力,可以作为氢氧化镍电极的添加剂。

A new manganese complex [Mn（muc）（H2O）3]·H2O（1）（H2muc=mucic acid） has been synthesized and characterized by X-ray single-crystal diffraction,elemental analysis,IR spectrum,and thermogravimetry analysis.The structure of 1 is composed of 1D chains and further joined by hydrogen bonds to construct a 3D supramolecule structure.Preliminary electrochemical experiments indicated that as an additive on nickel hydroxide electrodes 1 could improve the electrochemical performance and has potential applications in electrochemical storage.CCDC： 720478.