摘要
本文评述了费托合成反应机理的近期研究进展.详细讨论了费托合成反应碳化物机理基础上的烯烃再吸附理论.并指出随着表面科学技术的发展,深入到催化剂活性中心研究费托反应行为是深入认识费托反应机理的有效方法.这为费托合成反应机理及机理动力学的研究提供了新的方向和依据.
Recent advances in the mechanistic study of Fischer Tropsch synthesis are summarized in this review.The olefin readsorption mechanism based on the carbide mechanism is stressed in depth.Further,it is pointed out that an effective approach to the study of Fischer Tropsch mechanism exists in connection with the utilization of technologies of surface science,which may,as a useful tool,provide a way to understand the Fischer Tropsch reaction mechanism at the level of events over the active site/catalyst surface.This paper gives a new direction for the kinetics study of the reaction system.
出处
《内蒙古工业大学学报(自然科学版)》
1999年第2期121-127,共7页
Journal of Inner Mongolia University of Technology:Natural Science Edition
关键词
一氧化碳
烃
费托合成反应
催化剂
氢气
合成
Fischer Tropsch synthesis
reaction mechanism
olefin readsorption