期刊文献+

巯基三氮唑在铁表面电化学腐蚀行为的研究 被引量:1

Electrochemical Corrosion Behavior of Mercapto Triazole on Iron Surface
下载PDF
导出
摘要 通过电化学阻抗谱和极化曲线方法,在酸性腐蚀环境下,研究了巯基三氮唑在铁表面的腐蚀行为,研究结果表明:在铁/硫酸体系中,随着AAMT浓度的增加,缓释率逐渐增加,EIS和Tafel极化曲线测试结果基本一致。探讨了AAMT的缓释作用机理,AAMT属于对阴、阳极作用都有抑制的混合型缓蚀剂,主要是通过几何覆盖效应起缓释作用,为三氮唑类化合物的开发应用提供了理论和实验依据。 It was used the polarization curves and electrochemical impedance spectroscopy to study the corrosion behavior of AAMT in acid corrosion enviroment.The result showed that the inhibition efficiency was improved gradually with the concentration of AAMT increased.The polarization curves and electrochemical impedance spectroscopy were in good agreement.The inhibition mechanism of AAMT was discussed.It was found that AAMT can inhibit the cathode and anode.It was the mixed type inhibitor.The inhibition mechanism was geometric blocking effect.The results provided theoretical and experimental guidance for the indurstry development of triazole compounds.
出处 《广州化工》 CAS 2011年第9期63-65,72,共4页 GuangZhou Chemical Industry
基金 国家重点基础研究发展计划(973计划)(编号:2008CB617508)
关键词 巯基三氮唑 缓蚀剂 缓释机理 电化学方法 Mercapto Triazole inhibitor inhibition mechanism electrochemistry method
  • 相关文献

参考文献18

  • 1方景礼,叶向荣,李莹.缓蚀剂的作用机理[J].化学通报,1992(6):5-13. 被引量:35
  • 2Kdlmdn E. Trends in corrosion research [J]. Electrochim Acta, 2001, 46(24 -25) :3 607 -3 609.
  • 3Shimura, T. , Aramaki, K. Direct modification of a passivated iron electrode with alkyltriethoxysilanes for preventing passive film breakdown in a borate buffer containing 0.1M of chloride ion [J]. Corrosion Science, 2006, 48 ( 8 ) : 2 332 - 2 347.
  • 4Bentiss, F. , Michel Traisnel, Leon Gengembre, et al. Inhibition of acidic corrosion of mild steel by 3, 5 - dipheny1-4H - 1,2,4 - triazole [J]. Applied Surface Science, 2000, 161(1 -2) : 194 -202.
  • 5Chebabe. D, Z. Ait Chikh, A. Dermaj, et al. Synthesis of bolaamphiphile surfactants and their inhibitive effect on carbon steel corrosion in hydrochloric acid medium [ J ]. Corrosion Science, 2004, 46 (11): 2 701 -2 713.
  • 6Ebrini, M. Electrochemical and quantum chemical studies of new thiadiazole derivatives adsorption on mild steel in normal hydrochloric acid medium [J]. Corrosion Science, 2005, 47(2) : 485,505.
  • 7Ling - Guang Qiu, An - Jian Xie, et al. A novel triazole - based cationic gemini surfactant: synthesis and effect on corrosion inhibition of carbon steel in hydrochloric acid [ J ]. Materials Chemistry and Physics, 2005, 91(2-3): 269-273.
  • 8Diao Y. X. ,Han M. J. , Wan L. J. , et al. Adsorbed structures of 4,4 - bipyridine on Cu ( 111 ) in acid studied by STM and IR [ J ]. Langmuir, 2006, 22(8) : 3 640 -3 646.
  • 9Cruz, J. , E. Garcia- Ochoa, M. Castro. Experimental and theoretical study of the 3 - amino - 1,2,4 - triazole and 2 - aminothiazole corrosion inhibitors in carbon steel [ J]. Journal of the Electrochemical Society, 2003, 150(1) : B26 -B35.
  • 10Bentiss F, Traisnel M, Gengembre L, et al. A new triasole derivative as inhibitor of the acid corrosion of mild steel : electrochemical studies, weight loss determination, SEM and XPS [ J ]. Applied Surface Science, 1999, 152(3-4): 237-249.

二级参考文献13

  • 1方景礼,吴乃钧.XPS和AES研究铜表面PMTA防变色膜[J].中国腐蚀与防护学报,1989,9(4):280-288. 被引量:9
  • 2匿名著者,1976年
  • 3方景礼,表面技术,1991年,4期,9页
  • 4Plating,Plating Surface Finishing,1990年,77卷,2期,54页
  • 5石声泰,腐蚀与防护,1990年,11卷,4期,1页
  • 6方景礼,Sci Chin B,1989年,32卷,1期,23页
  • 7方景礼,Plating Surface Finishing,1988年,75卷,2期,58页
  • 8方景礼,中国科学.B,1988年,5期,355页
  • 9陆柱,全面腐蚀控制,1987年,1期,18页
  • 10Fang B S,Surf Sci,1986年,176卷,476页

共引文献34

同被引文献7

  • 1M.N. Khomami, I. Danaee, A.A. Attar, et al. Effects of NO2- and NO3- ions on corrosion of AISI 4130 steel in ethylene glycol plus water [J]. Transactions of the Indian Institute of Metals, 2012, 65 (3): 303 -311.
  • 2国家质量技术监督局.GB/T18175-2000水处理剂缓蚀性能的测定-旋转挂片法[S].北京:中国标准出版社,2000.
  • 3Y.N. Lou, S.Z. Song, W. X. Jin, et al. In field electrochemical evaluation of carbon steel corrosion in a marine test environment [ J ]. Anti -Corrosion Methods and Materials, 2009, 56(6) : 316 -322.
  • 4国家质量技术监督局.GB/T50050-2007工业循环冷却水处理设计规范[S].北京:中国标准出版社,2008.
  • 5沈忠,王青海,陈洁,何艺峰,张永浩,刘艳,刘莉.几种缓蚀剂对膨润土中16MnR钢的缓蚀作用[J].腐蚀与防护,2012,33(7):585-588. 被引量:2
  • 6方奇术,刘洪群,钟赵江.核电厂冷冻水管道涂层失效原因分析及解决建议[J].全面腐蚀控制,2012,26(11):54-58. 被引量:7
  • 7刘斌,金凯峰,谢建丽,刘涛,鲁俊东.低浓度亚硝酸盐对A106B碳钢材料腐蚀的影响[J].腐蚀与防护,2013,34(3):228-231. 被引量:7

引证文献1

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部