摘要
合成了环己基全取代五元瓜环(Cy5Q[5])与B i(NO3)3的配合物,通过单晶X-射线衍射方法进行了表征,该配合物形成了以Cy5Q[5]为"胶囊体"、氯离子为"胶囊"芯材、铋离子以及水分子为"胶囊盖"的"分子胶囊"结构,"分子胶囊"通过氢键作用交错地自组装形成超分子结构。
A single crystal was based on dodecyclohexanocucurbit[5]uril（Cy5Q[5]） with Bi（NO3）3,and structurally characterized by single crystal X-ray diffraction.The crystal structure of the complex shows that a chloride ion was encapsulated in Cy5Q[5] to form molecular capsule caped with Bi3＋ and water molecule,and the capsules was assembled through hydrogen bonding to form supramolecular structure.
出处
《贵州大学学报（自然科学版）》
2011年第2期28-30,共3页
Journal of Guizhou University:Natural Sciences
基金
贵州省科学技术基金项目(黔科合J字[2010]2005号)
关键词
环己基全取代五元瓜环
硝酸铋
晶体结构
Dodecyclohexanocucurbit[5]uril
Bismuth nitrate
crystal structure
