摘要
制备了曲克芦丁钯配合物,利用红外光谱分析仪、紫外光谱分析仪对配合物进行了表征.考察了催化剂对芳基卤与丙烯酸的Heck芳基化反应的催化性能.结果表明:曲克芦丁钯配合物能够有效地催化对芳基卤和丙烯酸的Heck芳基化反应,产率可达70%以上.尤其是对碘苯与丙烯酸的反应,具有更好的催化性能.
The complex of troxerutin-Pd was synthesized and the structure was characterizated by using IR spectroscopy and UV spectroscopy.The catalytic properties of complex were researched in the different conditions.The catalyst can catalyze Heck reaction of aryl halide with acrylic acid effectively,yield reached to 70 %.
出处
《河南科学》
2011年第5期524-528,共5页
Henan Science
基金
河南省科技发展计划项目(0624270040
092300410121)
