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New Reactions and Strategies in Highly Selective Organic Synthesis

New Reactions and Strategies in Highly Selective Organic Synthesis
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摘要 Organic synthetic chemistry is a core area of chemical research. The achievements in this field have greatly enhanced our life quality worldwide by providing an impressive range of useful man-made substances, materials and drugs. However, practical organic synthesis requires high selectivity, productivity, atom economy, cost efficiency, Organic synthetic chemistry is a core area of chemical research. The achievements in this field have greatly enhanced our life quality worldwide by providing an impressive range of useful man-made substances, materials and drugs. However, practical organic synthesis requires high selectivity, productivity, atom economy, cost efficiency,
出处 《Bulletin of the Chinese Academy of Sciences》 2011年第1期66-67,共2页 中国科学院院刊（英文版）
关键词 有机合成化学 高选择性 反应 原子经济性 化学研究 生活质量 成本效益 生产力
分类号 O621.3 [理学—有机化学]
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参考文献10

  • 1Yajima, A., Qin, Y. & Zhou, X. et al. (2008) Synthesis and absolute configuration of hormone al. Nat. Chem. Biol., 4, 235-237.
  • 2Yu, Z.P., Liu, X.H. & Dong, Z.H. et al. (2008) An N,N'dioxide/In(OTf)3 catalyst for the asymmetric hetero-diels-alder reaction between danishefsky's dienes and aldehydes: Application in the total synthesis of triketide. Angew. Chem. Int. Ed., 47(7), 1308-1311.
  • 3Yang, J., Wu, H.X. & Shen, L.Q. et al. (2007) Total synthesis of (+)-communesin F. J. Am. Chem. Soc., 129, 13794-13795.
  • 4Wu,H.X., Xue, F. & Xiao, X. et al. (2010) Synthesis of (+)-perophoramidine and determination of the absolute configuration. J. Am. Chem. Soc., 132, 14052-14054.
  • 5Li, W., Wang, J. & Hu, X.L. et al. (2010) Catalytic asymmetric roskamp reaction of a-alkyl-a-diazoesters with aromatic aldehydes: Highly enantioselective synthesis of a-alkyl-β-keto esters. J. Am. Chem. Soc., 132, 8532-8533.
  • 6Cai, Y.F., Liu, X.H. & Hui, Y.H et al. (2010) Catalytic asymmetric bromoamination of chalcones: Highly efficient synthesis of chiral a-bromo-β-amino ketone derivatives. Angew. Chem. Int. Ed., 49, 6160-6164.
  • 7Wang, J., Hu, X.L. & Jiang, J. et al. (2007) Asymmetric activation of tropos 2,2'-biphenol with cinchonine generating a remarkably effective catalyst for the asymmetric strecker reaction of N-Ts protected aldimines and ketoimines. Angew. Chem. Int. Ed., 46, 8468-8470.
  • 8Gao, G., Wang, Q. & Yu X.Q. et al (2006) Highty enantioselective synthesis of γ-hydroxy a,β-acetylenic esters by asymmetric alkyne addition to aldehydes. Angew. Chem. Int. Ed., 45, 122-125.
  • 9Han, B., Li, J.L. & Ma, C. et al. (2008) Organocatalytic asymmetric inverse electron demand aza diels-alder reaction of N-sulfonyl-1-aza-1,3-butadienes and aldehydes. Angew. Chem. Int. Ed., 47, 9971-9974.
  • 10Xi, P.H., Yang, F & Qin, S. et al. (2010) Palladium(II)-catalyzed oxidative C-H/C-H cross-coupling of heteroarenes. J. Am. Chem. Soc., 132, 1822-1824.
Bulletin of the Chinese Academy of Sciences
2011年 第1期

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