期刊文献+

黄铜矿细菌浸出机理及钝化原因研究进展 被引量:4

Research Progress on the Mechanism and Passivation of Chalcopyrite during Bioleaching Process
下载PDF
导出
摘要 细菌冶金技术由于成本低、污染少、流程短等优点,越来越受到人们重视,由于在常温下黄铜矿的细菌浸出速率较慢,有必要研究提高黄铜矿浸出速率的方法。综述了黄铜矿的细菌浸出机理以及黄铜矿的钝化原因。研究结果表明黄钾铁矾、硫层、中间产物层、高的溶液还原电位和黄铜矿稳定的晶体结构可能是黄铜矿细菌浸出过程中的钝化原因。 More and more people have been paying attention to the bioleaching technology due to the advantages of low cost,less pollution,shortened process.Because of the low bacterial leaching rate of chalcopyrite at room temperature,it was necessary to research the methods of improving leaching rate of chalcopyrite.Summarized the mechanism of bacterial leaching and the passivation of chalcopyrite.The results showed that jarosite,sulfur layer,intermediate layer,high value of the solution reduction potential and the stability of the chalcopyrite's crystal structure may be the passivation of the bacterial leaching of chalcopyrite.
出处 《金属矿山》 CAS 北大核心 2011年第5期75-80,共6页 Metal Mine
基金 国家高技术研究发展计划(863计划)项目(编号:2007AA060902)
关键词 黄铜矿 钝化 细菌浸出 电化学 Chalcopyrite Passivation Bioleaching Electrochemistry
  • 相关文献

参考文献25

  • 1Clrdoba E M, Munoz J A, Blazquez M L, et al. Leaching of chalcopylite with ferric ion, Part I : General aspects [ J ]. Hydrometallurgy ,2008,93:81-87.
  • 2舒荣波,阮仁满,温建康.黄铜矿生物浸出中钝化现象研究进展[J].稀有金属,2006,30(3):395-400. 被引量:26
  • 3Kratz T, Fuess H. Simultane strukturbestimmung yon kupferkies und bornit an einem kristall [ J ]. Zeitschrift fuer Kristallographie, 1989,186 : 167-169.
  • 4Singer P C, Stumm W. Acid mine drainage:The rate-determining step [ J ]. Science, 1970,167 : 1121-1123.
  • 5Rohwerder T,Gehrke T, Kinzler K, et al. Bioleaching review part A,Progress in bioleachillg: Fundamentals and mechanisms of bacterial metal sulfide oxidation [ J ]. Appl Microbiol Biotechnol, 2003,63 : 239 -248.
  • 6Hiroyoshi N, Hirota M, Hirajima T, et al. A case of terrous sulfate addition enhancing chalcopyrite leaching [ J] . Hydrometallurgy, 1997,47( 1 ) :37-45.
  • 7Hiroyoshi N, Miki H, Hirajima T,et al. A model for ferrous-promoted chalcopyrite leaching[ J ]. Hydromctallurgy ,2000:57 ( 1 ) : 31-38.
  • 8Hiroyoshi N, Mikl it, Hirajima T, et al. Enhancement of chalcopyrite leaching by ferrous ions in acidic ferric sulfate solutions [ J ]. Hydrometallurgy , 2001,60 ( 3 ) : 185-197.
  • 9Lazarn I. A rotating ring-disk study of the initial stages of the anodic dissolution of chalcopyrite in acidic solutions [ J ]. Journal of Applied Electrochemistry,2006,36:425-431.
  • 10Arce E M, Gonzalez I. A comparative study of electrochemical behavior of chalcopyrite ,chalcocite and bomite in sulfuric acid solution[J]. Int J Miner Process,2002,67:17-25.

二级参考文献22

  • 1Sand W.Novel mechanism for bioleaching of metal sulfides C.IBS'97.
  • 2Pinches A,et al.Leaching of chalcopyrite concentrates with Thiobacillus ferrooxidans in batch culture[J].Hydrometallurgy,1976,2:87.
  • 3Ake Sandstrom,et al.XPS characterisation of chalcopyrite chemically and bio-leached at high and low redox potential[J].Minerals Engineering,2005,18:505.
  • 4Third K A,et al.The role of iron-oxidizing bacteria in stimulation or in-hibition of chalcopyrite bioleaching[J].Hydrometallurgy,2000,57:225.
  • 5Parker A,et al.An X-ray photoelectron spectroscopy study of the mechanism of oxidative dissolution of chalcopyrite[J].Hydrometallurgy,2003,71:265.
  • 6Stott M B,et al.The role of iron-hydroxy precipitates in the passivation of chalcopyrite during bioleaching[J].Minerals Engineering,2000,13:1117.
  • 7Dutrizac J E.Elemental sulphur formation during the ferric sulphate leaching of chalcopyrite[J].Can.Metall Q,1989,28:337.
  • 8Craig Klauber,et al.Sulphur speciation of leached chalcopyrite surfaces as determined by X-ray photoelectron spectroscopy[J].Int.J.Miner.Process,2001,62:65.
  • 9Kinnunena P H M,et al.Chemical chalcopyrite leaching and biological ferric solvent production at pH below 1[C].IBS'2003.
  • 10Bevilaqua D,et al.Oxidative dissolution of chalcopyrite by Acidithiobacillus ferrooxidans analyzed by electrochemical impedance spectroscopy and atomic force microscopy[J].Bioelectrochemistry,2004,64:79.

共引文献25

同被引文献106

引证文献4

二级引证文献26

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部