摘要
将AlF3加入莫来石(莫来石/氧化锆)先质中,生坯试样经密闭处理及常压烧结,可获得莫来石柱状晶粒生长。实验结果表明:莫来石柱状生长使莫来石陶瓷在其强度不下降的前提下,韧性提高,且随柱状晶粒粒径增大而增加有类似架桥作用。ZTM(含AlF3)材料韧性的提高是由于莫来石柱状晶粒生长使t-ZrO2形态发生了变化,具有较大长径比或有尖角的不规则形态的t-ZrO2晶粒容易发生应力诱导相变。
AlF3 was added into mullite (mullite/ZrO2) precursor and then heat-treated in air tight conditionAfter sintered at high temperature,mullite/mullite(rod-like) and ZTM/mullite (rod-like) microstructures were obtainedThe growth of rod-like grains improved the fracture toughrness of mullite and the improvement increased as the diameter of rod-like grains increasedCrake bridging by rod-like grains was assumed to be the main toughening mechanism to mullite ceramicsIn ZTM,the t-ZrO2 grains with large aspect ratio or sharp angles caused by growth of rod-like mullite were easier to satisfy the critical stress condition of transformationThus the mechanical properties of ZTM material were improved obviously
出处
《硅酸盐通报》
CAS
CSCD
1999年第4期10-13,共4页
Bulletin of the Chinese Ceramic Society