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梯度共聚物的最新进展 被引量：2

The Latest Progress in Gradient Copolymer
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摘要 阐述了梯度共聚物的概念及梯度共聚物的研究意义,介绍了梯度共聚物分类及特点,以及与这些特点相对应的各种用途。重点综述了近年来各种梯度共聚物的制备方法如常规乳液聚合、原子转移自由基聚合(ATRP)、可逆加成-断裂链转移聚合(RAFP)和氮氧调控自由基聚合(NMCRP)等,以及梯度共聚物的各种表征方法,如红外光谱(FT-IR)、核磁共振(NMR)、薄层色谱(TLC)以及X射线光电子能谱(XPS),并进一步分析了梯度共聚物的研究方向和研究重点。 The concept, characteristics ,categories and research significance ,all kinds of applications of gradient copolymer were presented in this paper. The latest development of various preparing methods, such as conventional emulsion polymerization,atom transfer radical polymerization （ATRT） ,reversible addition fragmentation polymerization（RAFP） and nitroxide -mediated controlled radical polymerization（ NMCRP）, ere, and characterization methods of the gradient copolymers were reviewed , such as infrared spectrum（IR） ,nuclear magnetic resonance （ NMR）, thin layer chromatography （ TLC ） and X - ray photoelectron spectroscopy （XPS）. The development trend and main research topics of gradient copolymer in the future were also suggested.
作者 苏慧 魏霞 张心亚 陈焕钦
机构地区 华南理工大学
出处 《涂料工业》 CAS CSCD 北大核心 2011年第6期74-79,共6页 Paint & Coatings Industry
基金 国家自然科学基金(50803017)
关键词 梯度共聚物 原子转移自由基聚合 可逆加成-断裂链转移聚合 梯度共聚物的表征 gradient eopolymer atom transfer radical polymerization reversible addition fragmentation polymerization nitroxide -mediated controlled radical polymerization characterization of gradient eopolymers
分类号 TQ630.1 [化学工程—精细化工]
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参考文献41

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二级参考文献37

共引文献15

同被引文献59

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二级引证文献2

涂料工业
2011年 第6期

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