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CO、CO_2、H_2直接合成二甲醚与甲醇的化学平衡 被引量:3

Chemical Equilibrium for Direct Synthesis of Dimethyl Ether and Methanol from CO、CO_2、H_2
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摘要 由CO、CO_2、H_2直接合成二甲醚与甲醇为一复合反应体系,本文分别对CO加H_2、CO_2加H_2、合成气(即CO、CO_2同时加H_2)直接合成二甲醚与甲醇的化学平衡进行了计算,合成反应的单程转化率受到化学平衡的限制。 The direct synthesis of dimethyl ether and methanol from CO、CO_2、H_2 is a compound reaction system.Thermodynamic calculation is carried out respectively to the synthesis of dimethyl ether and methanol from (CO + H_2),(CO_2 + H_2 ) and (CO + CO_2 + H_2 ). The per pass conversion of the synthesis reaction is limited by chemical equilibrium.
出处 《煤化工》 CAS 1999年第3期29-32,共4页 Coal Chemical Industry
关键词 二甲醚 甲醇 化学平衡 一步法 氧化碳 dimethyl ether, methanol, chemical equilibrium
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  • 1汪俊锋,常杰,阴秀丽,付严.生物质气催化合成甲醇的研究[J].燃料化学学报,2005,33(1):58-61. 被引量:27
  • 2Jamil Toyir, Jose Luis G Fierro, Narcis Homs, et al. Catalytic Performance for CO2 Conversion to Methanol of Gallium- promoted Copper- based Catalysts:Influence of Metallic Precursors [ J ]. Applied Catalysis B: Environmental,2001,34:255 ~ 266
  • 3Soczynski J, Grabowski R, Lachowska M, et al. Effect of Mg and Mn Oxide on Structural and Adsorptive Properties of Cu/ZnO/ZrO2 Catalysts for the Methanol Synthesis from CO2 [ J ]. Applied Catalysis A: General, 2003,249:129~ 138
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  • 6Sardesai Abhay, Gunda Arun, Lee Sungyu, et al. Carbon Dioxide Tolerance in the Single - stage Liquid - phase Synthesis of Dimethyl Ether [ J ]. Energy Sources,2000,22( 1 ) :77 ~ 82
  • 7Wen Jie Shen, KiWon Jun, HoSuk Choi, et al. Thermodynamic Investigation of Methanol and Dimethyl Ether Synthesis from CO2 Hydrogenation [J]. Korean J. Chem. Eng. ,2000,17(2) :210 ~ 216
  • 8Carl L Yaws. Chemical Properties Handbook[ M]. MC Graw Hill Book Co.,1999
  • 9Wu Jingang, Masahiro Saito, Masami Takeuchi, et al. The Stability of Cu -ZnO Based Catalysts in Methanol Synthesis from A CO2 - rich Feed and from A CO - rich Feed[J]. Applied Catalysis A: General ,2001,218(2):235 ~240
  • 10葛庆杰,黄友梅,邱凤炎,李树本.CO_2加氢直接制取二甲醚的研究[J].分子催化,1997,11(4):297-300. 被引量:39

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