噻吩修饰的新型并五苯衍生物的合成及其光谱性能

Synthesis and Spectral Properties of Novel Oligothiophene-pentacene Derivatives

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摘要通过在并五苯的6-位和13-位引入寡聚噻吩取代基,成功地合成了三个噻吩修饰的并五苯衍生物(1a～1c),其结构经NMR,IR,MS和元素分析表征,其中1b和1c未见文献报道。并研究了1的甲苯溶液和固体薄膜的UV性能。 Three oligothiophene-pentacene derivatives（1a～1c） were successfully synthesized,which consist of pentacene skeletons modified by different oligothienyl groups at 6-site and 13-site.The structure was characterized by NMR,IR,MS and elemental analysis.1b and 1c are new compounds.The UV-Vis spectra of 1 in toluene and thin film were investigated.

作者王静刘珂

机构地区商丘师范学院化学系兰州大学功能有机分子化学国家重点实验室

出处《合成化学》 CAS CSCD 北大核心 2011年第3期318-320,共3页 Chinese Journal of Synthetic Chemistry

基金国家自然科学基金资助项目(20621091) 特种功能材料教育部重点实验室开放基金资助项目

关键词并五苯 SUZUKI偶联反应寡聚噻吩合成光谱性能 pentacene Suzuki coupling reaction oligothiophene synthesis spectral property

分类号 O626 [理学—有机化学]

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合成化学

2011年第3期

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噻吩修饰的新型并五苯衍生物的合成及其光谱性能

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