摘要
采用动态热流式差示扫描量热仪对自制改性偶氮二甲酰胺(AC)发泡剂进行了分析,并研究了其用量对聚氯乙烯(PVC)木塑复合材料力学性能的影响。结果表明,该改性AC发泡剂的分解温度在165~187℃,与传统AC发泡剂相比,分解温度降低约40℃,且峰值放热量降低了39.5%;改性AC发泡剂的平均发气量为189mL/mg;扫描电子显微镜分析表明,添加1.2份改性AC发泡剂时获得的PVC木塑复合材料的泡孔致密均匀,明显优于未改性的;与未发泡的材料相比,添加1.2份改性AC发泡剂时,PVC木塑复合材料的冲击强度提高了34.6%,表观密度降低了22.5%。
Performance of homemade modified composites was studied using differential azodicarbonamide(AC) foaming agent in PVC/wood scanning calorimeter. It was shown that the decomposition temperature of modified AC foaming agent was in the range from 165 ℃ to 187 ℃. Compared with the traditional AC foaming agent, the decomposition temperature was reduced by 40 ℃ and peak exothermic was also reduced by about 39. 5 %. The average gas evolution of modified AC was 189 mL/mg . When 1. 2 phr modified AC foaming agent was used, fine and uniform pores were obtained, which was witnessed by scanning electron microscope (SEM) micrographs. Compared with unfoamed PVC/wood composites, the impact strength of foamed composites increased by 34. 6 % and apparent density decreased by 22.5 % .
出处
《中国塑料》
CAS
CSCD
北大核心
2011年第5期65-69,共5页
China Plastics
基金
等学校科学研究基金资助项目(NJzy08161)
呼伦贝尔市科技计划项目资助(20090407)
关键词
聚氯乙烯
木塑复合材料
偶氮二甲酰胺
发泡剂
改性
力学性能
poly(vinyl chloride)
wood-plastic composite
azodicarbonamide
foaming agent
modification
mechanical property