混合配体、希土三元配合物的研究 Ⅳ.3,5—二硝基水扬酸(H_2DNSA)、邻菲咯啉(phen)、希土(RE)三元固体配合物的合成及性质

STUDY ON TERNARY COMPLEXES OF RARE EARTH ELEMENTS. IV.SYNTHESES AND PROPERTIES OF TERNARY COMPLEXESOF RARE EARTH ELEMENTS WITH 3,5-DINITROSALICYLIC ACID AND PHENANTHROLINE

本文报道了十种希土元素与3,5-二硝基水扬酸、邻菲咯啉三元配合物的制备方法。通过元素和化学分析测定了化合物的化学组成,并用红外光谱、紫外光谱、差热分析、磁化率、X射线粉天衍射等对所合成的化合物进行了结构和性质的研究。

The preparation of 10 ternary complexes of rare earth elements with 3,5-dinitrosalicylic acid (H2DNSA) and o-phenanthroline (phen) is reported in this article. The chemical composition of these complexes was ascertained by elementary and chemical analysis.IR and UV spectra, TG,magnetic susceptibility and X-ray diffraction analysis of the complexes were also studied.