期刊文献+

油田井筒防蜡剂的合成与性能表征 被引量:7

Synthesis and characterization of well paraffin inhibitor
下载PDF
导出
摘要 先合成侧链碳原子数为14~30的聚丙烯酸酯(PA)防蜡剂,再对聚丙烯酸酯类防蜡剂进行极性改性,考察改性PA防蜡剂的作用机制。结果表明:当侧链碳原子数等于26时PA防蜡剂效果较好;引入含氮的极性基团会改善防蜡剂的防蜡效果;当极性基团的摩尔分数为25%时防蜡剂的防蜡效果最好;防蜡剂的加入使原油中的蜡结晶成小晶体,由于电性排斥,蜡晶高度分散而稳定存在。 Polyacrylates(PA paraffin inhibitor) with the carbon numbers of the alkyl side chain C14~30 were synthesized.PA paraffin inhibitor was modified by adding polar agents.In addition,the action mechanism of the modified paraffin inhibitor was studied.The results show that when the carbon number of the alkyl side chain is 26,the effect of PA is the best.The introduction of nitrogen-containing polar groups into the molecule structure of PA improves its performance.When the polar groups mole fraction is 0.25,the performance of PA is the best.Paraffin inhibitor can make wax crystal become smaller shape.Wax crystal exists in steady dispersion state as a result of electric exclusion.
出处 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2011年第3期168-172,共5页 Journal of China University of Petroleum(Edition of Natural Science)
基金 国家'863'课题(2007AA06Z201)
关键词 防蜡剂 合成 蜡晶 聚丙烯酸酯 paraffin inhibitor synthesis wax crystal polyacrylates
  • 相关文献

参考文献14

  • 1JACK F T,ROBERT K P.Deposition apparatus to study the effects ofpolymers and aspartames upon wax deposition[J].Journal of Petroleum Science and Engineering,2010,72(1):166-174.
  • 2Jiang Qingzhe,Zhao Mifu,Song Zhaozheng,Ke Ming.Rheological Properties of Waxy Crude at a Low Temperature in the Presence of Pour Point Depressants[J].Petroleum Science,2005,2(4):62-65. 被引量:7
  • 3CHEN Wuhua,ZHAO Zongchang,YIN Caoyong.The interaction of waxes with pour point depressants[J].Fuel,2010,89(5):1127-1132.
  • 4JACK F T,ROBERT K P.Deposition apparatus to study the effects of polymers and asphaltenes upon wax deposition[J].Journal of Petroleum Science and Engineering,2010,72(1):166-174.
  • 5蒋庆哲,宋昭峥,葛际江,赵福麟.降凝剂对蜡晶晶格参数的影响[J].中国石油大学学报(自然科学版),2006,30(1):118-122. 被引量:25
  • 6ANDRE L C M,ELIZABETE F Lucas,GASPAR G.Poly(ethylene-co-vinyl acetate)(EVA)as wax inhibitor of a Brazilian crude oil:oil viscosity,pour point and phase behavior of organic solutions[J].Journal of Petroleum Science and Engineering,2001,32(4):159-165.
  • 7DELLYO A,ELIZABETE L.Chemical structure effect of (meth)acrylic ester copolymers and modified poly(ethylene-co-vinyl acetate)copolymer on paraffin deposition prevention in crude oil[J].Petroleum Science and Telechnology,2001,32(1):195-202.
  • 8JAFARI B T,GOLPASHA R,AKBARNIA H,et al.Effect of wax inhibitors on pour point and rheological properties of Iranian waxy crude oil[J].Fuel Processing Technology,2008,89(10):973-977.
  • 9宋昭峥,柯明,蒋庆哲,赵密福.降凝剂对原油蜡相变的影响[J].石油化工高等学校学报,2005,18(2):40-43. 被引量:13
  • 10CRISTANTE M,SELVES J.Structure-activity relationship study on paraffin inhibitors for crude oils[J].Analytica Chimica Acta,2003,284(2):303-316.

二级参考文献15

  • 1刘忠晖.降凝剂的筛选、评价及机理探讨[J].油气储运,1994,13(6):20-23. 被引量:13
  • 2廖克俭,张金辉,闫峰,刘发起.ESMVA降凝剂的研制[J].石油化工高等学校学报,1996,9(3):8-11. 被引量:6
  • 3KRISHNA R, JOSHI G. Correlations of pour point of gas oil and vacuum gas oil fractions with compositionalparameters [J]. Energy & Fuels, 1989,3(1): 15-20.
  • 4BROWN G L, GASKILL G P. Enhanced diesel fuel low temperature operability [J]. Nissenschaft & Technik,1990,43(5): 196-204.
  • 5HERAUD A, POULIGNY B. How does a cloud point diesel fuel additive work[J]. Journal of Colloid Interface Science, 1992,1153(2):379-390.
  • 6HOLDER G A, WINKLER D J. Crystal-growth poisoning of n-paraffln wax by polymeric additives and its relevance to polymer crystallization mechaniams[J]. Nature,1965,207(8):719-721.
  • 7RLUGG H P, ALEXANDER L E. X-ray diffraction procedures[M]. New York: John Wiley & Sons tnc,1966,349.
  • 8Maged M G, Chester W. Ethylene vinyl acetate and isobutylene terpolymer as a cold flow imploymer for distillate fuel compositions[ P]. US: 5681359,1999.
  • 9Iain M.Additiveflow oil properties[P].US:6106564,2000.
  • 10翟浩川,朱同荣,许白敏.聚丁二酰亚胺型润滑油降凝剂的研究[J].石油学报(石油加工),1999,15(3):68-76. 被引量:14

共引文献35

同被引文献25

引证文献7

二级引证文献19

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部