摘要
本文以LaFeAsO0.85F0.15超导材料为基体,在Fe位进行Zn取代力求保证材料超导性能的同时来改善材料的力学性能。采用固态反应法制备了Fe位Zn取代的LaFel-xZnxAsO0.85F0.15材料。XRD结果表明LaFe1-xZnAsO0.85F0.15为LaFeAsOo.85Fo.15与LaZnAsOo.85Fo.15两相复合材料。当Zn含量高达80%时,LaFe1-xZnxAsOo.85Fo.15材料仍然保持超导传输性能。LaFe-xZnxAsOo.85Fo15材料的显微硬度、弹性模量和断裂韧性随着Zn含量的增加明显提高。
LaFel-xZnxAsO0. 8sF0.15 were synthesized by solid state reaction to improve the mechanical properties while keep the superconductivity through substitution of Fe by Zn. XRD results indicate that LaFe1-xZnx AsO0. 85F0.15 are series of superconductive composites composed of LaFeAsOo. 85F0.15and LaZnAsOo. 85F0.15. LaFel-xZnx AsO0.85F0.15 can still keep the superconductive transport behavior even though the content of Zn reaches up to 80%. In addition, the mechanical properties of LaFel-xZnx AsO0.85F0.15 including microhardness, Young's Modulus and fracture toughness have been significantly improved by Zn substitution.
出处
《中国材料科技与设备》
2011年第3期48-50,共3页
Chinese Materials Science Technology & Equipment
关键词
超导材料
固态反应
复合材料
力学性能
Superconductor
Solid State Reaction
Composite
Mechanical Properties