三元混配化合物[Cu(8-Q)_2(phen)]·H_2O及[Cu(NCS)_2(phen)_2]·H_2O的固相合成

SYNTHESIS OF TERNARY MIXED LIGAND COMPLEX [Cu(8-Q)_2(phen)]·H_2O AND [Cu(NCS)_ 2(phen)_2]·H_2O IN SOLID STATE

用室温固相反应合成了［Ｃｕ（８－Ｑ）２（ｐｈｅｎ）］·Ｈ２Ｏ 及［Ｃｕ（ＮＣＳ）２（ｐｈｅｎ）２］·Ｈ２Ｏ 两个三元混配化合物。室温下［Ｃｕ（Ａｃ）２（Ｈ２Ｏ）］与邻菲?啉固体几乎不发生反应，但加入第二配体８－羟基喹啉及ＫＳＣＮ，反应几乎立即发生。ＸＲＤ、ＩＲ谱及元素分析结果表明：第二配体的加入并不仅仅促进［Ｃｕ（Ａｃ）２（Ｈ２Ｏ）］与第一配体的反应，它同时也参与反应，形成了三元混配化合物。

The ternary mixed ligand complexes[Cu(8 Q) 2(phen)]·H 2O and [Cu(NCS) 2(phen) 2]·H 2O(phen= 1,10 phenanthroline, 8 HQ=8 hydroxyquinoline)has been synthesized in solid state.[Cu(Ac) 2(H 2O)]can almost not react with 1,10 phen at room temperature. By using 8 HQ and KSCN as a second ligand respectively, the react can be carried out immediately. According to the results of EA, XRD,IR,the second ligand not only promote the reaction of [Cu(Ac) 2(H 2O)] with phen, but also participate in the reaction to produce a ternary mixed ligand complex. The synthesis of two ternary mixed ligand complexes in solid state at room temperature has not been reported up to now. $$$$