用结构参数Pi和P研究一些元素和无机物的能量性质

STUDIES ON THE ENERGIES OF SOME ELEMENTS AND INORGANIC COMPOUNDS WITH STRUCTRAL PARAMETERS Pi and P

在文献［１］中，作者曾对Ｒａｎｄｉｃ的价连接性值δν［２］作了改进，使其能适用于无机体系。本文将进一步考虑原子中电子之间的相互作用和总电子数对原子性质的影响，以期改进后的原子结构参数不仅能用于无机化合物体系。

Molecular structural parameter P was defined by atomic structural parameter P i. Using P i or P we corrlated the first ionic energies of 22 elements or the standard enthalpies of formation of TiX n (X=F, Cl, Br, I, n =1~4) and of the A mB n compounds (A=transition elements, B=F, Cl, Br, I), good linear relationships were obtained.