摘要
为了进一步研究在近共振电子态和非共振电子态转动能量传递的跃迁几率,以一阶含时波恩近似、各向异性Lennard—Jones相互作用势和直线轨迹近似为基础,我们建立了AB(1△,J)+c(slj)→AB(3∑,j')+c(slj')的碰撞诱导的电子态和转动态的能量传递模型,通过此模型我们得到了实验温度、转动量子数和折合质量对能量传递的影响.
To study theoretically the energy transfer that in the case of near resonant electronic and rotational that in the case of non resonant electronic, a model of energy transfer on AB(△,J)+c(slj)→AB(3∑,j')+c(slj') is presented,which based on the time dependent first order Born approximation, taking into account the anisotropic Lennard - Jones interaction potential and "straight-line" trajectory approximation, and we got the effect factor of energy transfer.
出处
《原子与分子物理学报》
CAS
CSCD
北大核心
2011年第3期473-478,共6页
Journal of Atomic and Molecular Physics
基金
辽宁省教育厅科技研究项目(2008290)
关键词
能量传递
共振电子态
量子干涉
energy transfer, near resonant electronic, quantumn interference