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Luminescence Characterization and Synthesis of γ-LiAlO_2:Eu^(3+) by Gel Combustion 被引量:2

Luminescence Characterization and Synthesis of γ-LiAlO_2:Eu^(3+) by Gel Combustion
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摘要 γ-LiAlO2:Eu3+(Eu3+:LAO) phosphor was obtained by gel combustion method using LiNO3,Al(NO3)3·9H2O,Eu(NO3)3·6H2O and citric acid as raw materials.The structure,morphology and luminescence were characterized by means of X-ray diffraction (XRD),scanning electron microscopy (SEM),photoluminescence (PL).The results demonstrated that the phosphor was pure-phase of flaky tetragonal crystal system with a mean size of around 1 μm.The strongest excitation peak was at 254 nm,belonging to the broadband excitation and the maximum emission peak was at 613 nm,corresponding to the 5D0→7F2 transition of Eu3+.Luminous intensity is closely related to the calcination temperature and doping concentration of Eu3+. γ-LiAlO2:Eu3+(Eu3+:LAO) phosphor was obtained by gel combustion method using LiNO3,Al(NO3)3·9H2O,Eu(NO3)3·6H2O and citric acid as raw materials.The structure,morphology and luminescence were characterized by means of X-ray diffraction (XRD),scanning electron microscopy (SEM),photoluminescence (PL).The results demonstrated that the phosphor was pure-phase of flaky tetragonal crystal system with a mean size of around 1 μm.The strongest excitation peak was at 254 nm,belonging to the broadband excitation and the maximum emission peak was at 613 nm,corresponding to the 5D0→7F2 transition of Eu3+.Luminous intensity is closely related to the calcination temperature and doping concentration of Eu3+.
出处 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2011年第3期434-438,共5页 武汉理工大学学报(材料科学英文版)
基金 Funded by Southwest University of Technology (No.08zx0103)
关键词 red phosphor γ-LiAlO2: Eu3+ gel combustion method rare earths red phosphor γ-LiAlO2: Eu3+ gel combustion method rare earths
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