丙酮溶剂化(2-氨基吡啶)(5,10,15,20-四苯基)卟啉镉(Ⅱ)的合成、晶体结构及光学性质

Synthesis,Crystal Structure and Spectroscopic Properties of Acetone Solvate(α-aminopyridine-N)(5,10,15,20-tetraphenylporphyrinato) Cadmium(Ⅱ)

合成了标题化合物丙酮溶剂化(2-氨基吡啶)(5,10,15,20-四苯基)卟啉镉(II)[Cd(TPP)(C5H6N2)]·CH3OCH3,并用X-射线衍射法测定了其晶体结构,该化合物属于三斜晶系,P-1空间群,晶胞参数为a=1.133 1(2)nm,b=1.327 5(3)nm,c=1.516 0(3)nm,Z=2,Dc=1.358 g.cm-3,μ=0.555 mm-1,F(000)=900,最终结构偏离因子R=0.038 7,Rw=0.099 8,S=1.084。通过红外光谱(IR)、紫外-可见光谱(UV-Vis)对化合物的光学性质进行了表征。

The title-mentioned compound [Cd （11） （TPP） （C5H6.N2）]. CH3OCH3 has been prepared and its crystal structure has been characterized by single crystal X-ray diffraction. This compound crystallizes in triclinic crystal system, space group P-1 with a = 1. 1331 {2） nm, b = 1.3275（3） n m, c = 1.5160（3） nm, Z = 2, Dc = 1.358g. cm^-3 , u = 0.555 mm^-1, F（000） = 900. The final R = 0.0387 and wR = 0.0998 and S = 1.084. The spectroscopic properties of this compound has been investigated by IR and UV-Vis methods.